Ultrafast Facile One Pot Synthesis of Meso-Tetraphenyl-Porphinato–Cu(II) Metal–Organic Frameworks (MOFs) for CO2 Capture

The present investigations introduce a new simple strategy to synthesize a crystalline copper metal–organic frameworks by high-energy He–Ag laser assisted synthesis for the first time in 18 min. The produced meso-tetraphenyl-porphinato–Cu(II) metal–organic frameworks (MOFs) were characterized by X-ray diffraction, scanning electron microscopy (SEM) and 3D-atomic force microscope (3D-AFM). Brunauer–Emmet–Teller BET specific surface area was measured and found 3418 m 2 g −1 . Furthermore meso-tetraphenyl-porphinato–Cu(II) metal–organic frameworks (MOFs) exhibit good sensitivity toward CO 2 -capture with an adsorption capacity of 76.66 mg CO 2 /g in 27.5 min at 25 °C, 40 bar.