Mixed- Ligand Phosphine and Arsine Complexes of Ruthenium (III) Ligated by Heterocyclic Thioamide

Mixed- Ligand Phosphine and Arsine Complexes of Ruthenium (III) Ligated by Heterocyclic Thioamide

Mixed ligands bis-chelates of general formula [RuX(EΦ3)(IPT5T)2] (X= Cl, Br, NCS or NO3; E= P/As) have been prepared and investigated. The ligand 1-phenyl tetrazoline -5-thione acts as bidentate (N,S) supported by IR, and 1HNMRspectral data. The distorted octahedral structure of all Ru(III) compound...

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Veröffentlicht in:Oriental journal of chemistry 2012, Vol.28 (4), p.1809-1813
Hauptverfasser: PANDEY, R.N., NAG, A.K., SHARMA, D.K.
Format: Artikel
Sprache:eng
Schlagworte:
Chelates
Coordination compounds
Ligands
Organic chemistry
Ruthenium
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Zusammenfassung:Mixed ligands bis-chelates of general formula [RuX(EΦ3)(IPT5T)2] (X= Cl, Br, NCS or NO3; E= P/As) have been prepared and investigated. The ligand 1-phenyl tetrazoline -5-thione acts as bidentate (N,S) supported by IR, and 1HNMRspectral data. The distorted octahedral structure of all Ru(III) compounds are assigned on the basis of elemental, magnetic and other physico-chemical data.
ISSN:0970-020X
2231-5039
DOI:10.13005/ojc/280434