One-pot transition-metal free transamidation to sterically hindered amides
One-pot synthesis of a variety of amides including sterically hindered amides from primary amides catalyzed by cesium fluoride has been developed for the first time. Primary amides provided sterically hindered amides in good yields (up to 86%), by transamidation, catalyzed by cesium fluoride, after...
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| Veröffentlicht in: | Organic Chemistry Frontiers 2018-10, Vol.5 (20), p.2950-2954 |
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| container_issue | 20 |
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| container_title | Organic Chemistry Frontiers |
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| creator | Guo, Weijie Huang, Jingjun Wu, Hongxiang Liu, Tingting Luo, Zhongfeng Jian, Junsheng Zeng, Zhuo |
| description | One-pot synthesis of a variety of amides including sterically hindered amides from primary amides catalyzed by cesium fluoride has been developed for the first time. Primary amides provided sterically hindered amides in good yields (up to 86%), by transamidation, catalyzed by cesium fluoride, after a simple Boc-activation. |
| doi_str_mv | 10.1039/C8QO00591E |
| format | Article |
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Primary amides provided sterically hindered amides in good yields (up to 86%), by transamidation, catalyzed by cesium fluoride, after a simple Boc-activation.</description><subject>Amides</subject><subject>Cesium</subject><subject>Cesium fluorides</subject><subject>Fluorides</subject><subject>Organic chemistry</subject><subject>Transition metals</subject><issn>2052-4129</issn><issn>2052-4110</issn><issn>2052-4129</issn><issn>2052-4110</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNpNkE9LxDAQxYMouKx78RMEvAnVTNppmqOU1VUWiqDnkm0n2KX_TLKH_fa2VNDTDPN-zHs8xm5BPICI9WOevRdCoIbtBVtJgTJKQOrLf_s123h_FEKAxFSgWrG3oqdoHAIPzvS-Cc3QRx0F03LriJar6ZrazAoPA_eBXFOZtj3zr6avyVHNZ4D8DbuypvW0-Z1r9vm8_ch30b54ec2f9lEVSwxRovUhTq2pMpuRBk0KZII1QjUlrNEcTKKU0soInBCZoiQrMEW0trJK1_Ga3S1_Rzd8n8iH8jicXD9ZlhJAgZYScKLuF6pyg_eObDm6pjPuXIIo57rKv7riH4RUXHE</recordid><startdate>20181021</startdate><enddate>20181021</enddate><creator>Guo, Weijie</creator><creator>Huang, Jingjun</creator><creator>Wu, Hongxiang</creator><creator>Liu, Tingting</creator><creator>Luo, Zhongfeng</creator><creator>Jian, Junsheng</creator><creator>Zeng, Zhuo</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QO</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>JG9</scope><scope>P64</scope><orcidid>https://orcid.org/0000-0003-4875-2909</orcidid></search><sort><creationdate>20181021</creationdate><title>One-pot transition-metal free transamidation to sterically hindered amides</title><author>Guo, Weijie ; Huang, Jingjun ; Wu, Hongxiang ; Liu, Tingting ; Luo, Zhongfeng ; Jian, Junsheng ; Zeng, Zhuo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c325t-499b36fac8f8e919e71245d51c412d5aba477797a05c8f2652ef05655ffcf79d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Amides</topic><topic>Cesium</topic><topic>Cesium fluorides</topic><topic>Fluorides</topic><topic>Organic chemistry</topic><topic>Transition metals</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Guo, Weijie</creatorcontrib><creatorcontrib>Huang, Jingjun</creatorcontrib><creatorcontrib>Wu, Hongxiang</creatorcontrib><creatorcontrib>Liu, Tingting</creatorcontrib><creatorcontrib>Luo, Zhongfeng</creatorcontrib><creatorcontrib>Jian, Junsheng</creatorcontrib><creatorcontrib>Zeng, Zhuo</creatorcontrib><collection>CrossRef</collection><collection>Biotechnology Research Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Organic Chemistry Frontiers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Guo, Weijie</au><au>Huang, Jingjun</au><au>Wu, Hongxiang</au><au>Liu, Tingting</au><au>Luo, Zhongfeng</au><au>Jian, Junsheng</au><au>Zeng, Zhuo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>One-pot transition-metal free transamidation to sterically hindered amides</atitle><jtitle>Organic Chemistry Frontiers</jtitle><date>2018-10-21</date><risdate>2018</risdate><volume>5</volume><issue>20</issue><spage>2950</spage><epage>2954</epage><pages>2950-2954</pages><issn>2052-4129</issn><issn>2052-4110</issn><eissn>2052-4129</eissn><eissn>2052-4110</eissn><abstract>One-pot synthesis of a variety of amides including sterically hindered amides from primary amides catalyzed by cesium fluoride has been developed for the first time. 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| fulltext | fulltext |
| identifier | ISSN: 2052-4129 |
| ispartof | Organic Chemistry Frontiers, 2018-10, Vol.5 (20), p.2950-2954 |
| issn | 2052-4129 2052-4110 2052-4129 2052-4110 |
| language | eng |
| recordid | cdi_proquest_journals_2117192215 |
| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Amides Cesium Cesium fluorides Fluorides Organic chemistry Transition metals |
| title | One-pot transition-metal free transamidation to sterically hindered amides |
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