One-pot transition-metal free transamidation to sterically hindered amides

One-pot transition-metal free transamidation to sterically hindered amides

One-pot synthesis of a variety of amides including sterically hindered amides from primary amides catalyzed by cesium fluoride has been developed for the first time. Primary amides provided sterically hindered amides in good yields (up to 86%), by transamidation, catalyzed by cesium fluoride, after...

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Veröffentlicht in:Organic Chemistry Frontiers 2018-10, Vol.5 (20), p.2950-2954
Hauptverfasser: Guo, Weijie, Huang, Jingjun, Wu, Hongxiang, Liu, Tingting, Luo, Zhongfeng, Jian, Junsheng, Zeng, Zhuo
Format: Artikel
Sprache:eng
Schlagworte:
Amides
Cesium
Cesium fluorides
Fluorides
Organic chemistry
Transition metals
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Zusammenfassung:One-pot synthesis of a variety of amides including sterically hindered amides from primary amides catalyzed by cesium fluoride has been developed for the first time. Primary amides provided sterically hindered amides in good yields (up to 86%), by transamidation, catalyzed by cesium fluoride, after a simple Boc-activation.
ISSN:2052-4129
2052-4110
2052-4129
2052-4110
DOI:10.1039/C8QO00591E