High-Temperature Raman Scattering Study of the Li2O–B2O3–MoO3 System: I. Detailed Comparison of the Structures of Molten Lithium and Potassium Molybdates

The structure and polymerization behavior of molybdenum–oxygen groups in molten lithium and potassium molybdates with different alkali-metal oxide to molybdenum oxide ratios have been studied by high-temperature Raman spectroscopy. The results are analyzed in comparison with the structural units of...

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Veröffentlicht in:	Inorganic materials 2018-10, Vol.54 (10), p.984-989
Hauptverfasser:	Sobol, A. A., Shukshin, V. E., Lukanin, V. I., Moiseeva, L. V.
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkali metals Boron oxides Chemistry Chemistry and Materials Science Industrial Chemistry/Chemical Engineering Inorganic Chemistry Lithium oxides Materials Science Molybdates Molybdenum Molybdenum oxides Molybdenum trioxide Potassium Raman spectra Raman spectroscopy
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Beschreibung
Zusammenfassung:	The structure and polymerization behavior of molybdenum–oxygen groups in molten lithium and potassium molybdates with different alkali-metal oxide to molybdenum oxide ratios have been studied by high-temperature Raman spectroscopy. The results are analyzed in comparison with the structural units of pure molybdenum oxide.
ISSN:	0020-1685 1608-3172
DOI:	10.1134/S0020168518100163