Synthesis of Fencholenic Aldehyde from α-pinene Epoxide on Modified Clays

Synthesis of Fencholenic Aldehyde from α-pinene Epoxide on Modified Clays

The conditions for isomerization of α-pinene epoxide (2,3-epoxypinane) on modified clays that gave comparatively high contents (33.0%) of fencholenic (iso-campholenic) aldehyde in the product mixture were determined. An effective method for isolating it was proposed. The structure of iso-campholenic...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemistry of natural compounds 2018-09, Vol.54 (5), p.893-897
Hauptverfasser: Sidorenko, A. Yu, Ignatovich, Zh. V., Ermolinskaya, A. L., Kravtsova, A. V., Baranovskii, A. V., Koroleva, E. V., Agabekov, V. E.
Format: Artikel
Sprache:eng
Schlagworte:
Clay
Isomerization
Medicine
NMR
Nuclear magnetic resonance
Organic Chemistry
Pharmacy
Plant Sciences
Two dimensional analysis
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The conditions for isomerization of α-pinene epoxide (2,3-epoxypinane) on modified clays that gave comparatively high contents (33.0%) of fencholenic (iso-campholenic) aldehyde in the product mixture were determined. An effective method for isolating it was proposed. The structure of iso-campholenic aldehyde was confirmed by analyzing 2D NOESY and HMBC NMR spectra.
ISSN:0009-3130
1573-8388
DOI:10.1007/s10600-018-2506-9