Physicochemical Properties of 3-Rutinoside-5,7,3',4'-tetrahydroxyflavone in Aqueous Solutions of Ethonium Surfactant

The effect ethonium, a dicationic surfactant, has on the physicochemical properties of a natural flavonoid, rutin, is studied spectrophotometrically in a wide range of concentrations in the region of physiological pH. It is found there are a bathochromic shift of the bands in the absorption spectra...

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Veröffentlicht in:Russian Journal of Physical Chemistry A 2018-09, Vol.92 (9), p.1706-1710
Hauptverfasser: Lipkovskaya, N. A., Barvinchenko, V. N.
Format: Artikel
Sprache:eng
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Zusammenfassung:The effect ethonium, a dicationic surfactant, has on the physicochemical properties of a natural flavonoid, rutin, is studied spectrophotometrically in a wide range of concentrations in the region of physiological pH. It is found there are a bathochromic shift of the bands in the absorption spectra of rutin, a drop in the apparent constant of its dissociation , and an increase in solubility and adsorption on the surface of nanosilica relative to aqueous solutions. The constant of bonding between rutin and ethonium is calculated.
ISSN:0036-0244
1531-863X
DOI:10.1134/S0036024418090169