Droplets Manipulated on Photothermal Organogel Surfaces

A photoresponsive organogel surface (POS), which integrates characteristics of the photothermal property of Fe3O4 nanoparticles and the low hysteresis feature of lubricant‐infused organogels, is shown. A photothermally induced dynamic temperature gradient can be formed rapidly at the location of near‐infrared‐light irradiation (NIR) on POS with suitable Fe3O4 nanoparticles content. Thus, various droplets (e.g., water, glycerol, ethylene glycol, propylene glycol, and ethanol) can be transported effectively and nimbly (e.g., along desired trajectories with controllable velocity and direction, even run uphill and deliver solid particles). This work reveals a synergistic effect between the asymmetrical droplet deformation and the inside Marangoni flows, which forms a unique driving force for droplet transport with high efficiency. This finding offers insight into the design of novel responsive interface materials for droplet transportation, which would be significant for laboratory‐on‐a‐chip contexts, mass transportation, and microengines. A synergistic effect between asymmetrical droplet deformation and the inside Marangoni flows forms a unique driving force for droplet transport with high efficiency on photothermal organogel surfaces.