Copolymers of N-Methyl-N-vinylacetamide with Allylidene Diacetate
New random copolymers containing protected aldehyde groups were prepared by radical copolymerization of N -methyl- N -vinylacetamide with allylidene diacetate. The relative activity constants were determined: for N -methyl- N -vinylacetamine, r 1 = 1.02 ± 0.015; for allylidene acetate, r 2 = 0.95 ±...
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Veröffentlicht in: | Russian journal of applied chemistry 2018-06, Vol.91 (6), p.1025-1028 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
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Online-Zugang: | Volltext |
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Zusammenfassung: | New random copolymers containing protected aldehyde groups were prepared by radical copolymerization of
N
-methyl-
N
-vinylacetamide with allylidene diacetate. The relative activity constants were determined: for
N
-methyl-
N
-vinylacetamine,
r
1
= 1.02 ± 0.015; for allylidene acetate,
r
2
= 0.95 ± 0.02. Removal of the acetyl protecting groups by base hydrolysis of allylidene diacetate units at 45–50°С yielded water-soluble
N
-methyl-
N
vinylacetamide copolymers with high content of acrolein units, promising for use as polymer carriers of biologically active compounds. |
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ISSN: | 1070-4272 1608-3296 |
DOI: | 10.1134/S1070427218060228 |