Single-order-parameter description of glass-forming liquids: A one-frequency test

Thermo-viscoelastic linear-response functions are calculated from the master equation describing viscous liquid inherent dynamics. From the imaginary parts of the frequency-dependent isobaric specific heat, isothermal compressibility, and isobaric thermal expansion coefficient, we define a "lin...

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Veröffentlicht in:arXiv.org 2007-02
Hauptverfasser: Ellegaard, Niels L, Christensen, Tage, Christiansen, Peder Voetmann, Niels Boye Olsen, Pedersen, Ulf R, Schrøder, Thomas B, Dyre, Jeppe C
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Sprache:eng
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Zusammenfassung:Thermo-viscoelastic linear-response functions are calculated from the master equation describing viscous liquid inherent dynamics. From the imaginary parts of the frequency-dependent isobaric specific heat, isothermal compressibility, and isobaric thermal expansion coefficient, we define a "linear dynamic Prigogine-Defay ratio" with the property that if this quantity is unity atone frequency, then it is unity at all frequencies. This happens if and only if there is a single-order-parameter description of the thermo-viscoelastic linear responses via an order parameter (which may be non-exponential in time). Generalizations to other cases of thermodynamic control parameters than temperature and pressure are treated in an Appendix.
ISSN:2331-8422
DOI:10.48550/arxiv.0610852