Single-order-parameter description of glass-forming liquids: A one-frequency test
Thermo-viscoelastic linear-response functions are calculated from the master equation describing viscous liquid inherent dynamics. From the imaginary parts of the frequency-dependent isobaric specific heat, isothermal compressibility, and isobaric thermal expansion coefficient, we define a "lin...
Gespeichert in:
Veröffentlicht in: | arXiv.org 2007-02 |
---|---|
Hauptverfasser: | , , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | Thermo-viscoelastic linear-response functions are calculated from the master equation describing viscous liquid inherent dynamics. From the imaginary parts of the frequency-dependent isobaric specific heat, isothermal compressibility, and isobaric thermal expansion coefficient, we define a "linear dynamic Prigogine-Defay ratio" with the property that if this quantity is unity atone frequency, then it is unity at all frequencies. This happens if and only if there is a single-order-parameter description of the thermo-viscoelastic linear responses via an order parameter (which may be non-exponential in time). Generalizations to other cases of thermodynamic control parameters than temperature and pressure are treated in an Appendix. |
---|---|
ISSN: | 2331-8422 |
DOI: | 10.48550/arxiv.0610852 |