Canonical formulation of Thermodynamics, and corresponding wave equation for far from equilibrium case

Lagrange and Hamilton equations for thermodynamic evolution near equilibrium as well as Schrodinger-like equation for the non-equilibrium case are obtained extending the CPDQ Principle (Constancy of the product momentum-oordinate uncertainty) to a new conjugate pair where the momentum f is the exten...

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Veröffentlicht in:arXiv.org 2011-09
1. Verfasser: Faigon, Adrian
Format: Artikel
Sprache:eng
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Zusammenfassung:Lagrange and Hamilton equations for thermodynamic evolution near equilibrium as well as Schrodinger-like equation for the non-equilibrium case are obtained extending the CPDQ Principle (Constancy of the product momentum-oordinate uncertainty) to a new conjugate pair where the momentum f is the extension of the mechanical f=p.{\delta}q product for the case the coordinate q is not directly observable. Applied to the case of a particle in a one dimension box, the results are in agreement with reported calculated and measured thermal conductance.
ISSN:2331-8422