Hybrid electrochemical/electrochromic Cu(II) ion sensor prototype based on PANI/ITO-electrode

[Display omitted] •Polyaniline (PANI) electrochromic films were deposited on Indium tin oxide (ITO).•Electrochromic performance of PANI/ITO-modified electrodes were investigated.•Sensitivity of PANI/ITO-modified electrode toward Cu(II) ions was evaluated.•Chemical structure of synthesized PANI layer...

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Veröffentlicht in:Sensors and actuators. B, Chemical Chemical, 2017-09, Vol.248, p.527-535
Hauptverfasser: Deshmukh, Megha A., Gicevicius, Mindaugas, Ramanaviciene, Almira, Shirsat, Mahendra D., Viter, Roman, Ramanavicius, Arunas
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container_issue
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container_title Sensors and actuators. B, Chemical
container_volume 248
creator Deshmukh, Megha A.
Gicevicius, Mindaugas
Ramanaviciene, Almira
Shirsat, Mahendra D.
Viter, Roman
Ramanavicius, Arunas
description [Display omitted] •Polyaniline (PANI) electrochromic films were deposited on Indium tin oxide (ITO).•Electrochromic performance of PANI/ITO-modified electrodes were investigated.•Sensitivity of PANI/ITO-modified electrode toward Cu(II) ions was evaluated.•Chemical structure of synthesized PANI layer was evaluated by FTIR. Conducting polymer polyaniline (PANI) based electrochromic films were electrochemically synthesized on indium tin oxide (ITO) covered glass electrodes and their electrochromic performances were investigated by spectroscopic methods before and after the incubation in Cu(II) ion containing aqueous solution. Chemical structure of synthesized PANI layer was evaluated by FTIR. The electrochromic performance of PANI film was determined by measuring of spectroscopic signals before and after the incubation of PANI film coated electrode in Cu(II) ion containing solution. During the change of potential, which was applied to PANI-modified electrode, the colour of PANI thin film turned from green to blue, dark blue, colorless and yellow dependently on the applied potential. Significant alteration of electrochromic effect was observed after the incubation of PANI/ITO-modified electrode in Cu(II) ion containing solution. It was also found that the PANI films exhibited highest optical contrast if potential profile of 0.200mV vs Ag/AgCl(3MKCl) was applied. Applicability of PANI/ITO-electrode for electrochromic effect based determination of Cu(II) ions was also evaluated. Investigated PANI/ITO-electrode response to Cu(II) ions indicates that PANI/ITO-electrodes can be used for both chronoamperometric and electrochromic detection of Cu(II) ions.
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Conducting polymer polyaniline (PANI) based electrochromic films were electrochemically synthesized on indium tin oxide (ITO) covered glass electrodes and their electrochromic performances were investigated by spectroscopic methods before and after the incubation in Cu(II) ion containing aqueous solution. Chemical structure of synthesized PANI layer was evaluated by FTIR. The electrochromic performance of PANI film was determined by measuring of spectroscopic signals before and after the incubation of PANI film coated electrode in Cu(II) ion containing solution. During the change of potential, which was applied to PANI-modified electrode, the colour of PANI thin film turned from green to blue, dark blue, colorless and yellow dependently on the applied potential. Significant alteration of electrochromic effect was observed after the incubation of PANI/ITO-modified electrode in Cu(II) ion containing solution. It was also found that the PANI films exhibited highest optical contrast if potential profile of 0.200mV vs Ag/AgCl(3MKCl) was applied. Applicability of PANI/ITO-electrode for electrochromic effect based determination of Cu(II) ions was also evaluated. Investigated PANI/ITO-electrode response to Cu(II) ions indicates that PANI/ITO-electrodes can be used for both chronoamperometric and electrochromic detection of Cu(II) ions.</description><identifier>ISSN: 0925-4005</identifier><identifier>EISSN: 1873-3077</identifier><identifier>DOI: 10.1016/j.snb.2017.03.167</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Chemical compounds ; Chemical synthesis ; Coated electrodes ; Conducting polymers ; Cyclic voltammetry ; Differential pulse voltammetry ; Electrochemical ; Electrochromic effect ; Electrochromism ; Electrodes ; Glass electrodes ; Heavy metal ion ; Indium tin oxides ; Organic chemistry ; PANI/ITO-electrode ; Polyanilines ; Polymers ; Prototypes ; Sensors ; Silver chloride</subject><ispartof>Sensors and actuators. B, Chemical, 2017-09, Vol.248, p.527-535</ispartof><rights>2017 Elsevier B.V.</rights><rights>Copyright Elsevier Science Ltd. 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B, Chemical</title><description>[Display omitted] •Polyaniline (PANI) electrochromic films were deposited on Indium tin oxide (ITO).•Electrochromic performance of PANI/ITO-modified electrodes were investigated.•Sensitivity of PANI/ITO-modified electrode toward Cu(II) ions was evaluated.•Chemical structure of synthesized PANI layer was evaluated by FTIR. Conducting polymer polyaniline (PANI) based electrochromic films were electrochemically synthesized on indium tin oxide (ITO) covered glass electrodes and their electrochromic performances were investigated by spectroscopic methods before and after the incubation in Cu(II) ion containing aqueous solution. Chemical structure of synthesized PANI layer was evaluated by FTIR. The electrochromic performance of PANI film was determined by measuring of spectroscopic signals before and after the incubation of PANI film coated electrode in Cu(II) ion containing solution. During the change of potential, which was applied to PANI-modified electrode, the colour of PANI thin film turned from green to blue, dark blue, colorless and yellow dependently on the applied potential. Significant alteration of electrochromic effect was observed after the incubation of PANI/ITO-modified electrode in Cu(II) ion containing solution. It was also found that the PANI films exhibited highest optical contrast if potential profile of 0.200mV vs Ag/AgCl(3MKCl) was applied. Applicability of PANI/ITO-electrode for electrochromic effect based determination of Cu(II) ions was also evaluated. 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B, Chemical</jtitle><date>2017-09-01</date><risdate>2017</risdate><volume>248</volume><spage>527</spage><epage>535</epage><pages>527-535</pages><issn>0925-4005</issn><eissn>1873-3077</eissn><abstract>[Display omitted] •Polyaniline (PANI) electrochromic films were deposited on Indium tin oxide (ITO).•Electrochromic performance of PANI/ITO-modified electrodes were investigated.•Sensitivity of PANI/ITO-modified electrode toward Cu(II) ions was evaluated.•Chemical structure of synthesized PANI layer was evaluated by FTIR. Conducting polymer polyaniline (PANI) based electrochromic films were electrochemically synthesized on indium tin oxide (ITO) covered glass electrodes and their electrochromic performances were investigated by spectroscopic methods before and after the incubation in Cu(II) ion containing aqueous solution. Chemical structure of synthesized PANI layer was evaluated by FTIR. The electrochromic performance of PANI film was determined by measuring of spectroscopic signals before and after the incubation of PANI film coated electrode in Cu(II) ion containing solution. During the change of potential, which was applied to PANI-modified electrode, the colour of PANI thin film turned from green to blue, dark blue, colorless and yellow dependently on the applied potential. Significant alteration of electrochromic effect was observed after the incubation of PANI/ITO-modified electrode in Cu(II) ion containing solution. It was also found that the PANI films exhibited highest optical contrast if potential profile of 0.200mV vs Ag/AgCl(3MKCl) was applied. Applicability of PANI/ITO-electrode for electrochromic effect based determination of Cu(II) ions was also evaluated. Investigated PANI/ITO-electrode response to Cu(II) ions indicates that PANI/ITO-electrodes can be used for both chronoamperometric and electrochromic detection of Cu(II) ions.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.snb.2017.03.167</doi><tpages>9</tpages></addata></record>
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subjects Chemical compounds
Chemical synthesis
Coated electrodes
Conducting polymers
Cyclic voltammetry
Differential pulse voltammetry
Electrochemical
Electrochromic effect
Electrochromism
Electrodes
Glass electrodes
Heavy metal ion
Indium tin oxides
Organic chemistry
PANI/ITO-electrode
Polyanilines
Polymers
Prototypes
Sensors
Silver chloride
title Hybrid electrochemical/electrochromic Cu(II) ion sensor prototype based on PANI/ITO-electrode
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