Pressure-induced isostructural phase transition and correlation of FeAs coordination with the superconducting properties of 111-type Na1-xFeAs

The effect of pressure on the crystalline structure and superconducting transition temperature (Tc) of the 111-type Na1-xFeAs system using in situ high pressure synchrotron x-ray powder diffraction and diamond anvil cell techniques is studied. A pressure-induced tetragonal to tetragonal isostructura...

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Veröffentlicht in:arXiv.org 2011-06
Hauptverfasser: Liu, Qingqing, Yu, Xiaohui, Wang, Xiancheng, Deng, Zheng, Lv, Yuxi, Zhu, Jinlong, Zhang, Sijia, Liu, Haozhe, Yang, Wenge, Wang, Lin, Mao, Hokwang, Shen, Guoyin, Lu, Zhongyi, Yang, Ren, Chen, Zhiqiang, Lin, Zhijun, Zhao, Yusheng, Jin, Changqing
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container_title arXiv.org
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creator Liu, Qingqing
Yu, Xiaohui
Wang, Xiancheng
Deng, Zheng
Lv, Yuxi
Zhu, Jinlong
Zhang, Sijia
Liu, Haozhe
Yang, Wenge
Wang, Lin
Mao, Hokwang
Shen, Guoyin
Lu, Zhongyi
Yang, Ren
Chen, Zhiqiang
Lin, Zhijun
Zhao, Yusheng
Jin, Changqing
description The effect of pressure on the crystalline structure and superconducting transition temperature (Tc) of the 111-type Na1-xFeAs system using in situ high pressure synchrotron x-ray powder diffraction and diamond anvil cell techniques is studied. A pressure-induced tetragonal to tetragonal isostructural phase transition was found. The systematic evolution of the FeAs4 tetrahedron as a function of pressure based on Rietveld refinements on the powder x-ray diffraction patterns was obtained. The non-monotonic Tc(P) behavior of Na1-xFeAs is found to correlate with the anomalies of the distance between the anion (As) and the iron layer as well as the bond angle between As-Fe-As for the two tetragonal phases. This behavior provides the key structural information in understanding the origin of the pressure dependence of Tc for 111-type iron pnictide superconductors. A pressure-induced structural phase transition is also observed at 20 GPa.
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A pressure-induced tetragonal to tetragonal isostructural phase transition was found. The systematic evolution of the FeAs4 tetrahedron as a function of pressure based on Rietveld refinements on the powder x-ray diffraction patterns was obtained. The non-monotonic Tc(P) behavior of Na1-xFeAs is found to correlate with the anomalies of the distance between the anion (As) and the iron layer as well as the bond angle between As-Fe-As for the two tetragonal phases. This behavior provides the key structural information in understanding the origin of the pressure dependence of Tc for 111-type iron pnictide superconductors. 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subjects Anomalies
Diamond anvil cells
Diffraction
Diffraction patterns
Group 5A compounds
Iron
Phase transitions
Pressure dependence
Pressure effects
Superconductivity
Synchrotron radiation
Tetrahedra
Transition temperature
X ray powder diffraction
X-ray diffraction
title Pressure-induced isostructural phase transition and correlation of FeAs coordination with the superconducting properties of 111-type Na1-xFeAs
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