Synthesis and luminescence of new water-soluble lanthanide complexes of DTTA-containing 4-(4-methoxyphenyl)-2,2′-bipyridine

[Display omitted] •Water-soluble luminescent lanthanide (Eu3+ and Tb3+) complexes containing 4-aryl-2,2′- bipyridine chromophore and a DTTA chelate.•These complexes exhibited large quantum yields of lanthanide luminescence with almost no residual ligand fluorescence.•Terbium luminescence was observe...

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Veröffentlicht in:Inorganica Chimica Acta 2018-06, Vol.478, p.49-53
Hauptverfasser: Krinochkin, Alexey P., Kopchuk, Dmitry S., Kim, Grigory A., Gorbunov, Eugeny B., Kovalev, Igor S., Santra, Sougata, Zyryanov, Grigory V., Majee, Adinath, Rusinov, Vladimir L., Chupakhin, Oleg N.
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Sprache:eng
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Zusammenfassung:[Display omitted] •Water-soluble luminescent lanthanide (Eu3+ and Tb3+) complexes containing 4-aryl-2,2′- bipyridine chromophore and a DTTA chelate.•These complexes exhibited large quantum yields of lanthanide luminescence with almost no residual ligand fluorescence.•Terbium luminescence was observed for new complexes.•4-Aryl-2,2′-bipyridine chromophores are promising sensitizers of lanthanide luminescence. A new DTTA-appended 4-(4-methoxyphenyl)-2,2′-bipyridine ligand has been synthesized for lanthanide cations by Kröhnke method. Its luminescent lanthanide (Eu3+ and Tb3+) water-soluble complexes have been synthesized. The photophysical properties of new chelates were studied. Comparison of the new complexes with the known ones has been done; in some cases a red-shift in absorption spectra and higher lanthanide emission quantum yields were observed.
ISSN:0020-1693
1873-3255
DOI:10.1016/j.ica.2018.03.016