Synthesis and luminescence of new water-soluble lanthanide complexes of DTTA-containing 4-(4-methoxyphenyl)-2,2′-bipyridine
[Display omitted] •Water-soluble luminescent lanthanide (Eu3+ and Tb3+) complexes containing 4-aryl-2,2′- bipyridine chromophore and a DTTA chelate.•These complexes exhibited large quantum yields of lanthanide luminescence with almost no residual ligand fluorescence.•Terbium luminescence was observe...
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Veröffentlicht in: | Inorganica Chimica Acta 2018-06, Vol.478, p.49-53 |
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Format: | Artikel |
Sprache: | eng |
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•Water-soluble luminescent lanthanide (Eu3+ and Tb3+) complexes containing 4-aryl-2,2′- bipyridine chromophore and a DTTA chelate.•These complexes exhibited large quantum yields of lanthanide luminescence with almost no residual ligand fluorescence.•Terbium luminescence was observed for new complexes.•4-Aryl-2,2′-bipyridine chromophores are promising sensitizers of lanthanide luminescence.
A new DTTA-appended 4-(4-methoxyphenyl)-2,2′-bipyridine ligand has been synthesized for lanthanide cations by Kröhnke method. Its luminescent lanthanide (Eu3+ and Tb3+) water-soluble complexes have been synthesized. The photophysical properties of new chelates were studied. Comparison of the new complexes with the known ones has been done; in some cases a red-shift in absorption spectra and higher lanthanide emission quantum yields were observed. |
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ISSN: | 0020-1693 1873-3255 |
DOI: | 10.1016/j.ica.2018.03.016 |