Free-radical anti-Markovnikov hydroalkylation of unactivated alkenes with simple alkanes

Free-radical anti-Markovnikov hydroalkylation of unactivated alkenes with simple alkanes

A Cu( ii )-mediated radical anti-Markovnikov hydroalkylation of unactivated alkenes with simple alkanes via selective C(sp 3 )–H bond cleavage was achieved. This reaction features high site-selectivity diverse functional group tolerance, and scalability.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Green chemistry : an international journal and green chemistry resource : GC 2018, Vol.20 (15), p.3432-3435
Hauptverfasser: Tian, Yunfei, Ling, Anbo, Fang, Ren, Tan, Ren Xiang, Liu, Zhong-Quan
Format: Artikel
Sprache:eng
Schlagworte:
Alkanes
Alkenes
Copper
Functional groups
Green chemistry
Hydrogen bonds
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A Cu( ii )-mediated radical anti-Markovnikov hydroalkylation of unactivated alkenes with simple alkanes via selective C(sp 3 )–H bond cleavage was achieved. This reaction features high site-selectivity diverse functional group tolerance, and scalability.
ISSN:1463-9262
1463-9270
DOI:10.1039/C8GC01394B