Exploring the Performance Improvement of the Oxygen Evolution Reaction in a Stable Bimetal–Organic Framework System

Despite wide applications of bimetallic electrocatalysis in oxygen evolution reaction (OER) owing to their superior performance, the origin of the improved performance remains elusive. The underlying mechanism was explored by designing and synthesizing a series of stable metal–organic frameworks (MOFs: NNU‐21–24) based on trinuclear metal carboxylate clusters and tridentate carboxylate ligands. Among the examined stable MOFs, NNU‐23 exhibits the best OER performance; particularly, compared with monometallic MOFs, all the bimetallic MOFs display improved OER activity. DFT calculations and experimental results demonstrate that introduction of the second metal atom can improve the activity of the original atom. The proposed model of bimetallic electrocatalysts affecting their OER performance can facilitate design of efficient bimetallic catalysts for energy storage and conversion, and investigation of the related catalytic mechanisms. Der Austausch eines Eisenatoms in einem Fe3‐Cluster durch ein anderes Metallatom ergibt Fe2M‐Cluster, die als Knotenpunkte mit organischen Brückenliganden zum Aufbau von Dimetall‐MOFs kombiniert werden können. Die Einführung des zweiten Metalls kann die Leistungsfähigkeit des Materials in der elektrokatalytischen Sauerstoffentwicklung verbessern.