Synthesis of β‐Trifluoromethylated Alkyl Azides via a Manganese‐Catalyzed Trifluoromethylazidation of Alkenes with CF3SO2Na and TMSN3

Synthesis of β‐Trifluoromethylated Alkyl Azides via a Manganese‐Catalyzed Trifluoromethylazidation of Alkenes with CF3SO2Na and TMSN3

A convenient and efficient manganese‐catalyzed trifluoromethylazidation of alkenes has been developed by utilizing inexpensive and readily available CF3SO2Na under mild conditions. The various β‐trifluoromethylated alkyl azides were directly obtained from corresponding allyl, vinyl, chain terminal a...

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Veröffentlicht in:Advanced synthesis & catalysis 2018-07, Vol.360 (14), p.2659-2667
Hauptverfasser: Zhang, Yuecheng, Han, Xulin, Zhao, Jiquan, Qian, Zijian, Li, Tianmei, Tang, Yuqing, Zhang, Hong‐Yu
Format: Artikel
Sprache:eng
Schlagworte:
Alkenes
Azidotrimethylsilane
Chemical synthesis
Manganese
Manganese-catalyzed
Sodium trifluoromethanesulfinate
Trifluoromethylazidation
β-trifluoromethylated Alkyl Azides
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Zusammenfassung:A convenient and efficient manganese‐catalyzed trifluoromethylazidation of alkenes has been developed by utilizing inexpensive and readily available CF3SO2Na under mild conditions. The various β‐trifluoromethylated alkyl azides were directly obtained from corresponding allyl, vinyl, chain terminal and internal alkenes, and easily further transformed into other CF3‐containing compounds.
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.201800488