Self-assembled samarium selenide nanorods as a new electrode material for reliable supercapacitors

[Display omitted] •The cross-linked samarium selenide nanorods were self-assembled by chemical route.•The Sm2Se3 nanorods showed a maximum specific capacitance of 316 F g−1.•The Sm2Se3 nanorods exhibited cycling stability of 87% after 1000 cycles. For the first time, cross-linked nanorods of samariu...

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Veröffentlicht in:Materials letters 2018-07, Vol.223, p.45-48
Hauptverfasser: Kumbhar, V.S., Lokhande, A.C., Chodankar, N.R., Gaikwad, N.S., Lokhande, C.D.
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Sprache:eng
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Zusammenfassung:[Display omitted] •The cross-linked samarium selenide nanorods were self-assembled by chemical route.•The Sm2Se3 nanorods showed a maximum specific capacitance of 316 F g−1.•The Sm2Se3 nanorods exhibited cycling stability of 87% after 1000 cycles. For the first time, cross-linked nanorods of samarium selenide (Sm2Se3) were self-assembled using the chemical route for reliable supercapacitors. The X-ray diffraction and X-ray photoelectron spectroscopy techniques confirmed the formation of crystalline Sm2Se3. The formation of Sm2Se3 across-linked nanorods was confirmed by field emission scanning electron microscopy technique. The cyclic voltammetry, charge-discharge, and electrochemical impedance spectroscopy were used to study the supercapacitive properties of the electrode. The highly porous network of the electrode resulted from this assembly exhibited excellent capacitive behavior with a maximum specific capacitance (316 F g−1) and cycling stability (87%) for 1000 charge-discharge cycles.
ISSN:0167-577X
1873-4979
DOI:10.1016/j.matlet.2018.04.016