Palladium-catalyzed reductive electrocarboxylation of allyl esters with carbon dioxide

Palladium-catalyzed reductive electrocarboxylation of allyl esters with carbon dioxide

Palladium-catalyzed regioselective electrocarboxylation of homostyrenyl acetates with CO 2 has been successfully developed, providing α-aryl carboxylic acids with good selectivity and yield. In addition, the catalytic asymmetric carboxylation of cinnamyl acetate has been demonstrated, despite modera...

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Veröffentlicht in:Organic Chemistry Frontiers 2018-07, Vol.5 (14), p.2244-2248
Hauptverfasser: Jiao, Ke-Jin, Li, Zhao-Ming, Xu, Xue-Tao, Zhang, Li-Pu, Li, Yi-Qian, Zhang, Kun, Mei, Tian-Sheng
Format: Artikel
Sprache:eng
Schlagworte:
Acetates
Acetic acid
Aromatic compounds
Carbon dioxide
Carboxylation
Carboxylic acids
Catalysis
Enantiomers
Esters
Organic chemistry
Palladium
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Zusammenfassung:Palladium-catalyzed regioselective electrocarboxylation of homostyrenyl acetates with CO 2 has been successfully developed, providing α-aryl carboxylic acids with good selectivity and yield. In addition, the catalytic asymmetric carboxylation of cinnamyl acetate has been demonstrated, despite moderate enantioselectivity.
ISSN:2052-4129
2052-4110
2052-4129
2052-4110
DOI:10.1039/C8QO00507A