One-Pot Synthesis of 2-Alkylsulfanyldihydrofuran Derivatives from Tetracyanocyclopropyl Ketones

One-Pot Synthesis of 2-Alkylsulfanyldihydrofuran Derivatives from Tetracyanocyclopropyl Ketones

Successive treatment of 3-acylcyclopropane-1,1,2,2-tetracarbonitriles with sodium hydrogen carbonate and alkylmercaptan in water environment results in the formation of 2-(5-amino-2-aryl-2-alkyl-sulfanyl-4-cyano-2,3-dihydrofuran-3-ylidene)propanedinitriles.

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Bibliographische Detailangaben
Veröffentlicht in:Russian journal of organic chemistry 2018-05, Vol.54 (5), p.795-798
Hauptverfasser: Grigor’ev, A. A., Karpov, S. V., Vasil’ev, A. N., Nasakin, O. E., Gracheva, Yu. A., Kayukova, O. V., Kayukov, Ya. S.
Format: Artikel
Sprache:eng
Schlagworte:
Aromatic compounds
Chemistry
Chemistry and Materials Science
Ketones
Organic Chemistry
Short Communications
Sodium bicarbonate
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Zusammenfassung:Successive treatment of 3-acylcyclopropane-1,1,2,2-tetracarbonitriles with sodium hydrogen carbonate and alkylmercaptan in water environment results in the formation of 2-(5-amino-2-aryl-2-alkyl-sulfanyl-4-cyano-2,3-dihydrofuran-3-ylidene)propanedinitriles.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428018050226