Information-entropic measures for non-zero l states of confined hydrogen-like ions
Rényi entropy ( R ), Tsallis entropy ( T ), Shannon entropy ( S ), and Onicescu energy ( E ) are studied in a spherically confined H atom (CHA), in conjugate space, with special emphasis on non-zero l states. Representative calculations are done by employing exact analytical wave functions in r spac...
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Veröffentlicht in: | The European physical journal. D, Atomic, molecular, and optical physics Atomic, molecular, and optical physics, 2018-06, Vol.72 (6), p.1-13, Article 118 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Rényi entropy (
R
), Tsallis entropy (
T
), Shannon entropy (
S
), and Onicescu energy (
E
) are studied in a spherically confined H atom (CHA), in conjugate space, with special emphasis on non-zero
l
states. Representative calculations are done by employing
exact
analytical wave functions in
r
space. Accurate
p
space-wave functions are generated numerically by performing Fourier transform on respective
r
-space counterparts. These are extended for H-isoelectronic series by applying the scaling relations.
R
,
T
are evaluated by choosing the order of entropic moments (
α
,
β
) as (3/5, 3) in
r
and
p
spaces. Detailed, systematic results of all these measures with respect to variations of confinement radii
r
c
are offered for arbitrary
n
,
l
quantum numbers. For a given
n
, at small
r
c
,
R
r
α
,
T
r
α
,
S
r
collapse with rise of
l
, attain a minimum, then again grow up. Growth in
r
c
shifts the point of inflection towards higher
l
values. An increase in
Z
enhances localization of a particular state. Several other new interesting inferences are uncovered. Comparison with literature results (available only for
S
in 2
p
, 3
d
states), offers excellent agreement.
Graphical abstract |
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ISSN: | 1434-6060 1434-6079 |
DOI: | 10.1140/epjd/e2018-90104-1 |