Recyclable switching between nonporous and porous phases of a square lattice () topology coordination network

Recyclable switching between nonporous and porous phases of a square lattice () topology coordination network

A nonporous square lattice ( sql ) coordination network [Co(bipy) 2 (NCS) 2 ] n ( sql-1-Co-NCS ) exhibits recyclable switching induced by CO 2 . The sorption isotherms are stepped with moderate hysteresis, temperature controlled and saturation uptake is fixed. Such switching, which has rarely been o...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2018, Vol.54 (51), p.742-745
Hauptverfasser: Wang, Shi-Qiang, Yang, Qing-Yuan, Mukherjee, Soumya, O'Nolan, Daniel, Patyk-Ka mierczak, Ewa, Chen, Kai-Jie, Shivanna, Mohana, Murray, Claire, Tang, Chiu C, Zaworotko, Michael J
Format: Artikel
Sprache:eng
Schlagworte:
Carbon dioxide
Query languages
Sorption
Switching
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Zusammenfassung:A nonporous square lattice ( sql ) coordination network [Co(bipy) 2 (NCS) 2 ] n ( sql-1-Co-NCS ) exhibits recyclable switching induced by CO 2 . The sorption isotherms are stepped with moderate hysteresis, temperature controlled and saturation uptake is fixed. Such switching, which has rarely been observed, offers the promise of exceptional working capacity for gas storage. A 2D switching material holds great potential for exceptional working capacity of gas storage.
ISSN:1359-7345
1364-548X
DOI:10.1039/c8cc03838d