Frontispiece: Majority‐Rules Effect and Allostery in Molecular Recognition of Calix[4]arene‐Based Triple‐Stranded Metallohelicates

Triple‐stranded metallohelicates possessing the internal guest binding cavities surrounded by the calix[4]arene units are depicted in the graphic. The chirality of a guest is transferred to the helicity of the helicates. The majority‐rules effects in the chiral guest binding are found in the helicat...

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Veröffentlicht in:Chemistry : a European journal 2018-06, Vol.24 (34), p.n/a
Hauptverfasser: Yamasaki, Yutaro, Shio, Hidemi, Amimoto, Tomoko, Sekiya, Ryo, Haino, Takeharu
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Sprache:eng
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Zusammenfassung:Triple‐stranded metallohelicates possessing the internal guest binding cavities surrounded by the calix[4]arene units are depicted in the graphic. The chirality of a guest is transferred to the helicity of the helicates. The majority‐rules effects in the chiral guest binding are found in the helicates possessing the conformationally‐coupled guest binding sites. For more information see the Full Paper by T. Haino et al. on page 8558 ff.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201883465