A one-step laser process for rapid manufacture of mesoscopic perovskite solar cells prepared under high relative humidity

Mesoscopic perovskite solar cells (PSCs) containing a TiO 2 mesoporous structure and a compact TiO 2 film have reached the highest power conversion efficiency (PCE) and excellent stability among various PSC structures. However, conventional fabrication of the mesoscopic structure requires high-tempe...

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Veröffentlicht in:Sustainable energy & fuels 2018, Vol.2 (6), p.1216-1224
Hauptverfasser: Chen, Qian, Mokhtar, Muhamad Z., Ke, Jack Chun-Ren, Thomas, Andrew G., Hadi, Aseel, Whittaker, Eric, Curioni, Michele, Liu, Zhu
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Sprache:eng
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Zusammenfassung:Mesoscopic perovskite solar cells (PSCs) containing a TiO 2 mesoporous structure and a compact TiO 2 film have reached the highest power conversion efficiency (PCE) and excellent stability among various PSC structures. However, conventional fabrication of the mesoscopic structure requires high-temperature heating processes that are considerably time-consuming. Current methods also make it difficult to fabricate integrated or multifunctional devices on the same substrate. Laser processing offers an opportunity to develop a rapid, localized and precise treatment without damaging the substrate or surrounding materials. Here, we demonstrate a rapid and localized one-step fiber laser process to generate both mesoporous and compact TiO 2 films on tin-doped indium oxide (ITO) glass. The average PCE obtained for the PSCs by laser irradiation for 1 min, prepared under a high relative humidity of around 60% by a one-step deposition method, is equivalent to that by furnace treatment for 2 h. A fundamental understanding of the laser sintering mechanism using a fiber laser with a wavelength of 1070 nm has also been established. The use of the fiber laser with a wall-plug efficiency of over 40% offers an economically feasible, industrially viable solution to the challenge of rapid fabrication of mesoscopic PSCs and integration of multifunctional devices. In addition, it opens a novel route to manufacture tandem, patterned or aesthetic solar cells in the future.
ISSN:2398-4902
2398-4902
DOI:10.1039/C8SE00043C