(Z)-2-[(1-Phenylsulfonyl-1H-indol-3-yl)methylene]-1-azabicyclo[2.2.2]octan-3-one semicarbazone
In crystals of the title compound, C23H23N5O3S, the indole system is planar and the phenyl ring of the phenylsulfonyl group makes a dihedral angle with the best plane of the indole system of 77.18 (4) degrees. The olefinic bond connecting the azabicyclic and indole systems has Z geometry. The geomet...
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| Veröffentlicht in: | Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2007-05, Vol.63 (5), p.o277 |
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| container_issue | 5 |
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| container_title | Acta crystallographica. Section C, Crystal structure communications |
| container_volume | 63 |
| creator | Sonar, Vijayakumar N Venkatraj, M Parkin, Sean Crooks, Peter A |
| description | In crystals of the title compound, C23H23N5O3S, the indole system is planar and the phenyl ring of the phenylsulfonyl group makes a dihedral angle with the best plane of the indole system of 77.18 (4) degrees. The olefinic bond connecting the azabicyclic and indole systems has Z geometry. The geometry adopted by the C=O bond with respect to the N--N bond is trans. The O atom of the carbonyl group of each molecule is hydrogen bonded to the hydrazidic H atom of an adjacent molecule to form an eight-membered-ring dimeric structure. [PUBLICATION ABSTRACT] |
| doi_str_mv | 10.1107/S0108270107006129 |
| format | Article |
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The olefinic bond connecting the azabicyclic and indole systems has Z geometry. The geometry adopted by the C=O bond with respect to the N--N bond is trans. The O atom of the carbonyl group of each molecule is hydrogen bonded to the hydrazidic H atom of an adjacent molecule to form an eight-membered-ring dimeric structure. [PUBLICATION ABSTRACT]</description><identifier>ISSN: 0108-2701</identifier><identifier>EISSN: 1600-5759</identifier><identifier>DOI: 10.1107/S0108270107006129</identifier><language>eng</language><publisher>Chester: Wiley Subscription Services, Inc</publisher><subject>Chemical bonds ; Chemical compounds ; Crystal structure ; Crystallography ; Geometry</subject><ispartof>Acta crystallographica. 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The geometry adopted by the C=O bond with respect to the N--N bond is trans. The O atom of the carbonyl group of each molecule is hydrogen bonded to the hydrazidic H atom of an adjacent molecule to form an eight-membered-ring dimeric structure. [PUBLICATION ABSTRACT]</abstract><cop>Chester</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1107/S0108270107006129</doi></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0108-2701 |
| ispartof | Acta crystallographica. Section C, Crystal structure communications, 2007-05, Vol.63 (5), p.o277 |
| issn | 0108-2701 1600-5759 |
| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete; Alma/SFX Local Collection |
| subjects | Chemical bonds Chemical compounds Crystal structure Crystallography Geometry |
| title | (Z)-2-[(1-Phenylsulfonyl-1H-indol-3-yl)methylene]-1-azabicyclo[2.2.2]octan-3-one semicarbazone |
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