(Z)-2-[(1-Phenyl­sulfonyl-1H-indol-3-yl)methyl­ene]-1-aza­bicyclo­[2.2.2]octan-3-one semicarbazone

(Z)-2-[(1-Phenyl­sulfonyl-1H-indol-3-yl)methyl­ene]-1-aza­bicyclo­[2.2.2]octan-3-one semicarbazone

In crystals of the title compound, C23H23N5O3S, the indole system is planar and the phenyl ring of the phenylsulfonyl group makes a dihedral angle with the best plane of the indole system of 77.18 (4) degrees. The olefinic bond connecting the azabicyclic and indole systems has Z geometry. The geomet...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2007-05, Vol.63 (5), p.o277
Hauptverfasser: Sonar, Vijayakumar N, Venkatraj, M, Parkin, Sean, Crooks, Peter A
Format: Artikel
Sprache:eng
Schlagworte:
Chemical bonds
Chemical compounds
Crystal structure
Crystallography
Geometry
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:In crystals of the title compound, C23H23N5O3S, the indole system is planar and the phenyl ring of the phenylsulfonyl group makes a dihedral angle with the best plane of the indole system of 77.18 (4) degrees. The olefinic bond connecting the azabicyclic and indole systems has Z geometry. The geometry adopted by the C=O bond with respect to the N--N bond is trans. The O atom of the carbonyl group of each molecule is hydrogen bonded to the hydrazidic H atom of an adjacent molecule to form an eight-membered-ring dimeric structure. [PUBLICATION ABSTRACT]
ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270107006129