Three-dimensional iron() porous coordination polymer exhibiting carbon dioxide-dependent spin crossover
We report a three-dimensional Fe( ii ) porous coordination polymer that exhibits a spin crossover temperature change following CO 2 sorption (though not N 2 sorption). Furthermore, single crystals of the desolvated polymer with CO 2 molecules at three different temperatures were characterised by X-r...
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Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2018, Vol.54 (34), p.4262-4265 |
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container_title | Chemical communications (Cambridge, England) |
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creator | Shin, Jong Won Jeong, Ah Rim Jeoung, Sungeun Moon, Hoi Ri Komatsumaru, Yuki Hayami, Shinya Moon, Dohyun Min, Kil Sik |
description | We report a three-dimensional Fe(
ii
) porous coordination polymer that exhibits a spin crossover temperature change following CO
2
sorption (though not N
2
sorption). Furthermore, single crystals of the desolvated polymer with CO
2
molecules at three different temperatures were characterised by X-ray crystallography.
A three-dimensional iron(
ii
) porous coordination polymer has been observed spin crossover behaviours through the sorption of H
2
O and CO
2
, respectively. |
doi_str_mv | 10.1039/c8cc00678d |
format | Article |
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ii
) porous coordination polymer that exhibits a spin crossover temperature change following CO
2
sorption (though not N
2
sorption). Furthermore, single crystals of the desolvated polymer with CO
2
molecules at three different temperatures were characterised by X-ray crystallography.
A three-dimensional iron(
ii
) porous coordination polymer has been observed spin crossover behaviours through the sorption of H
2
O and CO
2
, respectively.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c8cc00678d</identifier><identifier>PMID: 29578229</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Carbon dioxide ; Coordination polymers ; Crystallography ; Iron ; Polymers ; Single crystals ; Sorption</subject><ispartof>Chemical communications (Cambridge, England), 2018, Vol.54 (34), p.4262-4265</ispartof><rights>Copyright Royal Society of Chemistry 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c403t-6ba9c65847ae1291f276585bdf246677706591880dde30c4bdca0404143ae083</citedby><cites>FETCH-LOGICAL-c403t-6ba9c65847ae1291f276585bdf246677706591880dde30c4bdca0404143ae083</cites><orcidid>0000-0001-8392-2382 ; 0000-0001-8777-2174 ; 0000-0002-6967-894X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,4022,27922,27923,27924</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/29578229$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Shin, Jong Won</creatorcontrib><creatorcontrib>Jeong, Ah Rim</creatorcontrib><creatorcontrib>Jeoung, Sungeun</creatorcontrib><creatorcontrib>Moon, Hoi Ri</creatorcontrib><creatorcontrib>Komatsumaru, Yuki</creatorcontrib><creatorcontrib>Hayami, Shinya</creatorcontrib><creatorcontrib>Moon, Dohyun</creatorcontrib><creatorcontrib>Min, Kil Sik</creatorcontrib><title>Three-dimensional iron() porous coordination polymer exhibiting carbon dioxide-dependent spin crossover</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>We report a three-dimensional Fe(
ii
) porous coordination polymer that exhibits a spin crossover temperature change following CO
2
sorption (though not N
2
sorption). Furthermore, single crystals of the desolvated polymer with CO
2
molecules at three different temperatures were characterised by X-ray crystallography.
A three-dimensional iron(
ii
) porous coordination polymer has been observed spin crossover behaviours through the sorption of H
2
O and CO
2
, respectively.</description><subject>Carbon dioxide</subject><subject>Coordination polymers</subject><subject>Crystallography</subject><subject>Iron</subject><subject>Polymers</subject><subject>Single crystals</subject><subject>Sorption</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNpdkUtLxDAUhYMovjfulYKbUagmTdKkS6lPGHAzC3clTe5opE1q0hH992ZmfIB3k8f5OHDOReiI4AuCaXWppdYYl0KaDbRLaMlyzuTT5vLOq1xQxnfQXoyvOA3hchvtFBUXsiiqXfQ8ewkAubE9uGi9U11mg3eTs2zwwS9ipr0Pxjo1JjH9dZ89hAw-XmxrR-ueM61CmxRj_Yc1yQgGcAbcmMXBukwHH6N_h3CAtuaqi3D4fe6j2e3NrL7Pp493D_XVNNcM0zEvW1XpkksmFJCiIvNCpBdvzbxgZSmEwCWviJTYGKBYs9ZohRlmhFEFWNJ9NFnbDsG_LSCOTW-jhq5TDlKapsBElsmIkoSe_kNf_SKkApYUxQXjouKJOl9TqyQB5s0QbK_CZ0Nws2y_qWVdr9q_TvDJt-Wi7cH8oj91J-B4DYSof9W_9dEvK-eJxg</recordid><startdate>2018</startdate><enddate>2018</enddate><creator>Shin, Jong Won</creator><creator>Jeong, Ah Rim</creator><creator>Jeoung, Sungeun</creator><creator>Moon, Hoi Ri</creator><creator>Komatsumaru, Yuki</creator><creator>Hayami, Shinya</creator><creator>Moon, Dohyun</creator><creator>Min, Kil Sik</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-8392-2382</orcidid><orcidid>https://orcid.org/0000-0001-8777-2174</orcidid><orcidid>https://orcid.org/0000-0002-6967-894X</orcidid></search><sort><creationdate>2018</creationdate><title>Three-dimensional iron() porous coordination polymer exhibiting carbon dioxide-dependent spin crossover</title><author>Shin, Jong Won ; Jeong, Ah Rim ; Jeoung, Sungeun ; Moon, Hoi Ri ; Komatsumaru, Yuki ; Hayami, Shinya ; Moon, Dohyun ; Min, Kil Sik</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c403t-6ba9c65847ae1291f276585bdf246677706591880dde30c4bdca0404143ae083</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Carbon dioxide</topic><topic>Coordination polymers</topic><topic>Crystallography</topic><topic>Iron</topic><topic>Polymers</topic><topic>Single crystals</topic><topic>Sorption</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shin, Jong Won</creatorcontrib><creatorcontrib>Jeong, Ah Rim</creatorcontrib><creatorcontrib>Jeoung, Sungeun</creatorcontrib><creatorcontrib>Moon, Hoi Ri</creatorcontrib><creatorcontrib>Komatsumaru, Yuki</creatorcontrib><creatorcontrib>Hayami, Shinya</creatorcontrib><creatorcontrib>Moon, Dohyun</creatorcontrib><creatorcontrib>Min, Kil Sik</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shin, Jong Won</au><au>Jeong, Ah Rim</au><au>Jeoung, Sungeun</au><au>Moon, Hoi Ri</au><au>Komatsumaru, Yuki</au><au>Hayami, Shinya</au><au>Moon, Dohyun</au><au>Min, Kil Sik</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Three-dimensional iron() porous coordination polymer exhibiting carbon dioxide-dependent spin crossover</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2018</date><risdate>2018</risdate><volume>54</volume><issue>34</issue><spage>4262</spage><epage>4265</epage><pages>4262-4265</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>We report a three-dimensional Fe(
ii
) porous coordination polymer that exhibits a spin crossover temperature change following CO
2
sorption (though not N
2
sorption). Furthermore, single crystals of the desolvated polymer with CO
2
molecules at three different temperatures were characterised by X-ray crystallography.
A three-dimensional iron(
ii
) porous coordination polymer has been observed spin crossover behaviours through the sorption of H
2
O and CO
2
, respectively.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>29578229</pmid><doi>10.1039/c8cc00678d</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0001-8392-2382</orcidid><orcidid>https://orcid.org/0000-0001-8777-2174</orcidid><orcidid>https://orcid.org/0000-0002-6967-894X</orcidid></addata></record> |
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ispartof | Chemical communications (Cambridge, England), 2018, Vol.54 (34), p.4262-4265 |
issn | 1359-7345 1364-548X |
language | eng |
recordid | cdi_proquest_journals_2030245795 |
source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
subjects | Carbon dioxide Coordination polymers Crystallography Iron Polymers Single crystals Sorption |
title | Three-dimensional iron() porous coordination polymer exhibiting carbon dioxide-dependent spin crossover |
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