Three-dimensional iron() porous coordination polymer exhibiting carbon dioxide-dependent spin crossover

Three-dimensional iron() porous coordination polymer exhibiting carbon dioxide-dependent spin crossover

We report a three-dimensional Fe( ii ) porous coordination polymer that exhibits a spin crossover temperature change following CO 2 sorption (though not N 2 sorption). Furthermore, single crystals of the desolvated polymer with CO 2 molecules at three different temperatures were characterised by X-r...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2018, Vol.54 (34), p.4262-4265
Hauptverfasser: Shin, Jong Won, Jeong, Ah Rim, Jeoung, Sungeun, Moon, Hoi Ri, Komatsumaru, Yuki, Hayami, Shinya, Moon, Dohyun, Min, Kil Sik
Format: Artikel
Sprache:eng
Schlagworte:
Carbon dioxide
Coordination polymers
Crystallography
Iron
Polymers
Single crystals
Sorption
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:We report a three-dimensional Fe( ii ) porous coordination polymer that exhibits a spin crossover temperature change following CO 2 sorption (though not N 2 sorption). Furthermore, single crystals of the desolvated polymer with CO 2 molecules at three different temperatures were characterised by X-ray crystallography. A three-dimensional iron( ii ) porous coordination polymer has been observed spin crossover behaviours through the sorption of H 2 O and CO 2 , respectively.
ISSN:1359-7345
1364-548X
DOI:10.1039/c8cc00678d