M/Gd0.1Ti0.1Zr0.1Ce0.7O2 Catalysts Where M Is Pt, Pd, or Pt–Pd in CO Oxidation

Catalysts where the support was a nanodisperse solid solution of Gd 0.1 Ti 0.1 Zr 0.1 Ce 0.7 O 2 and the active component was Pd, Pt, or Pd–Pt were obtained. The support was synthesized by co-precipitation with sonication. Palladium and platinum acetylacetonates were used as the precursors. The samp...

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Veröffentlicht in:Inorganic materials : applied research 2018, Vol.9 (2), p.239-242
Hauptverfasser: Liberman, E. Yu, Zagaynov, I. V., Koneva, E. A.
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Sprache:eng
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Zusammenfassung:Catalysts where the support was a nanodisperse solid solution of Gd 0.1 Ti 0.1 Zr 0.1 Ce 0.7 O 2 and the active component was Pd, Pt, or Pd–Pt were obtained. The support was synthesized by co-precipitation with sonication. Palladium and platinum acetylacetonates were used as the precursors. The samples were studied by X-ray powder diffraction (XRD), X-ray fluorescence (XRF), transmission electron microscopy (TEM), and low-temperature nitrogen adsorption. The catalytic activity of the resulting samples in CO oxidation was measured by the flow method. Palladium-containing sample was the most active. The temperature of complete CO oxidation increases in the order Pd > Pd–Pt > Pt. The synthesized catalysts are of interest in detoxification of gas emissions.
ISSN:2075-1133
2075-115X
DOI:10.1134/S2075113318020181