Formation of the P–C and C–C bonds in the Reaction of 2-(5-Methyl-2-phenyl-2H-1,2,3-diazaphosphol-4-yl)-4H-benzo[e]-1,3,2-dioxaphosphorin-4-one with Dimethyl Acetylenedicarboxylate under Mild Conditions

2-(5-Methyl-2-phenyl-2 H -1,2,3-diazaphosphol-4-yl)-4 H -benzo[ e ]-1,3,2-dioxaphosphorin-4-one reacts under mild conditions with dimethyl acetylenedicarboxylate with the participation by only threecoordinated phosphorus atom and the formation of 2-(5-methyl-2-phenyl-2 H -1,2,3-diazaphosphol-4-yl)-3...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Russian journal of general chemistry 2018-03, Vol.88 (3), p.605-606
Hauptverfasser: Mironov, V. F., Ivkova, G. A., Musin, R. Z., Abdrakhmanova, L. M.
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:2-(5-Methyl-2-phenyl-2 H -1,2,3-diazaphosphol-4-yl)-4 H -benzo[ e ]-1,3,2-dioxaphosphorin-4-one reacts under mild conditions with dimethyl acetylenedicarboxylate with the participation by only threecoordinated phosphorus atom and the formation of 2-(5-methyl-2-phenyl-2 H -1,2,3-diazaphosphol-4-yl)-3,4-dimethoxycarbonylbenzo[f]-1,2-oxaphosphepine-2,5-dione. During the process, simultaneous formation of the P–C and C–C bonds takes place.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363218030350