Synthesis of Tricyclic Diesters from 8-Acetoxytricyclodec-3-ene Monoester

Synthesis of Tricyclic Diesters from 8-Acetoxytricyclodec-3-ene Monoester

Tricyclic diesters were synthesized in yields of 70.4–90.8% by the addition of С 2 –С 5 monobasic carboxylic acids to tricyclo[5.2.1.0 2,6 ]dec-3-еn-8-yl acetate in the presence of a BF 3 ·OEt 2 catalyst. One of the synthesized diesters, tricyclodec-3,8-diyl diacetate, has a pleasant smell with a ci...

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Veröffentlicht in:Russian journal of general chemistry 2018-03, Vol.88 (3), p.393-396
Hauptverfasser: Mamedov, M. K., Makhmudova, E. G., Rasulova, R. A., Abdullaeva, A. Dzh
Format: Artikel
Sprache:eng
Schlagworte:
Acetic acid
Carboxylic acids
Chemical synthesis
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Dicyclopentadiene
Diesters
Organic compounds
Smell
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Zusammenfassung:Tricyclic diesters were synthesized in yields of 70.4–90.8% by the addition of С 2 –С 5 monobasic carboxylic acids to tricyclo[5.2.1.0 2,6 ]dec-3-еn-8-yl acetate in the presence of a BF 3 ·OEt 2 catalyst. One of the synthesized diesters, tricyclodec-3,8-diyl diacetate, has a pleasant smell with a citrus scent and can be used in different perfume compositions as a flavoring.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363218030039