Nanostructured Pyrophosphate Na2PdP2O7‐Catalyzed Suzuki‐Miyaura Cross‐Coupling Under Microwave Irradiation

Nanostructured palladium pyrophosphate (Na2PdP2O7) catalyst was synthesized and well characterized by using different techniques (TGA, XRD, SEM, TEM...). This nanocatalyst exhibited excellent catalytic activity in the synthesis of biaryl compounds via Suzuki‐Miyaura cross‐coupling to produce their corresponding products in good to excellent yields under mild conditions. The catalyst is recyclable and was recycled for four runs for the reaction of 4‐bromoacetophenone with phenylboronic acid without appreciable loss of its catalytic activity. Nanostructured palladium pyrophosphate (Na2PdP2O7) catalyst was synthesized and well characterized by using different techniques (TGA, XRD, SEM, TEM...). This nanocatalyst exhibited excellent catalytic activity in the synthesis of biaryl compounds via Suzuki‐Miyaura cross‐coupling to produce their corresponding products in good to excellent yields under mild conditions.