Morphology-selective synthesis of Cu(NO3)2·2.5H2O micro/nanostructures achieved by rational manipulation of nucleation pathways and their morphology-preserved conversion to CuO porous micro/nanostructures

A special Cu(NO3)2 thin solution layer was built on highly hydrophilic mica surfaces and subjected to rapid evaporation. Controlling the evaporation time can intentionally manipulate the supersaturation. Morphology-selective synthesis of nanoplate- or microsphere-like Cu(NO3)2·2.5H2O micro/nanostruc...

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Veröffentlicht in:CrystEngComm 2018-01, Vol.20 (12), p.1731-1738
Hauptverfasser: Feng, Feng, Chen, Muzi, Ji Hong Wu
Format: Artikel
Sprache:eng
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Zusammenfassung:A special Cu(NO3)2 thin solution layer was built on highly hydrophilic mica surfaces and subjected to rapid evaporation. Controlling the evaporation time can intentionally manipulate the supersaturation. Morphology-selective synthesis of nanoplate- or microsphere-like Cu(NO3)2·2.5H2O micro/nanostructures has been succeeded by alternatively boosting either the heterogeneous nucleation at the substrate–solution interface at a low supersaturation level or the homogeneous nucleation in the bulk solution phase at a high supersaturation level. Our study presents a new method for morphology-selective synthesis of micro/nanostructures, which should also be applicable to materials other than Cu(NO3)2·2.5H2O and shall actually promote their applications. As a demonstration, Cu(NO3)2·2.5H2O micro/nanostructures were converted into porous CuO with well-preserved starting morphologies. The hierarchical porous CuO micro/nanostructures exhibited easily recyclable high photocatalytic activity towards visible-light degradation of methylene blue (MB).
ISSN:1466-8033
DOI:10.1039/c8ce00049b