Ion Mobility In Complex Antimony(III) Sulfate Fluorides M6Sb4(SO4)3F12 (M = Rb, Cs, NH4) and (NH4)2Sb(SO4)F3 According to 19F and 1Н NMR Data

Ion Mobility In Complex Antimony(III) Sulfate Fluorides M6Sb4(SO4)3F12 (M = Rb, Cs, NH4) and (NH4)2Sb(SO4)F3 According to 19F and 1Н NMR Data

19 F and 1 Н NMR methods were used to study ion mobility in M 6 Sb 4 (SO 4 ) 3 F 12 (M = Rb, Cs, NH 4 ) and (NH 4 ) 2 Sb(SO 4 )F 3 complex antimony(III) sulfate fluorides with alkali cations and ammonium. The types of ionic mobility in these compounds were identified at 150–470 K.

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Veröffentlicht in:Journal of structural chemistry 2018, Vol.59 (1), p.47-52
Hauptverfasser: Kavun, V. Ya, Zemnukhova, L. A., Polyantsev, M. M.
Format: Artikel
Sprache:eng
Schlagworte:
Antimony
Atomic
Atomic/Molecular Structure and Spectra
Chemistry
Chemistry and Materials Science
Fluorides
Inorganic Chemistry
Ionic mobility
Ions
Molecular
NMR
Nuclear magnetic resonance
Optical and Plasma Physics
Physical Chemistry
Solid State Physics
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Zusammenfassung:19 F and 1 Н NMR methods were used to study ion mobility in M 6 Sb 4 (SO 4 ) 3 F 12 (M = Rb, Cs, NH 4 ) and (NH 4 ) 2 Sb(SO 4 )F 3 complex antimony(III) sulfate fluorides with alkali cations and ammonium. The types of ionic mobility in these compounds were identified at 150–470 K.
ISSN:0022-4766
1573-8779
DOI:10.1134/S0022476618010080