Nonenzymatic and enzymatic hydrolysis of alkyl halides: A theoretical study of the S(N)2 reactions of acetate and hydroxide ions with alkyl chlorides

Nonenzymatic and enzymatic hydrolysis of alkyl halides: A theoretical study of the S(N)2 reactions of acetate and hydroxide ions with alkyl chlorides

The S(N)2 displacements of chloride ion from CH(3)Cl, C(2)H(5)Cl and C(2)H(4)Cl(2) are investigated.

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Veröffentlicht in:Proceedings of the National Academy of Sciences - PNAS 1997-06, Vol.94 (13), p.6591
Hauptverfasser: Maulitz, Andreas H, Lightstone, Felice C, Zheng, Ya-Jun, Bruice, Thomas C
Format: Artikel
Sprache:eng
Schlagworte:
Chemical reactions
Chemistry
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Zusammenfassung:The S(N)2 displacements of chloride ion from CH(3)Cl, C(2)H(5)Cl and C(2)H(4)Cl(2) are investigated.
ISSN:0027-8424
1091-6490
DOI:10.1073/pnas.94.13.6591