Hydrosilylation of Allyl Ethers in the Presence of Supported Sulfur-Containing Platinum(II) Complexes

Hydrosilylation of Allyl Ethers in the Presence of Supported Sulfur-Containing Platinum(II) Complexes

Hydrosilylation of allyl ethyl, allyl butyl, allyl glycidyl, allyl benzyl, and allyl phenyl ethers by 1,1,3,3-tetramethyldisiloxane in the presence of supported sulfur-containing platinum(II) complexes with the general formula [{SiO 2 }O 2S i(Me)(CH 2 ) 3 SR] 2 PtCl 2 (R = Bu, Hex, Bn; {SiO 2 } is s...

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Veröffentlicht in:Russian journal of general chemistry 2018, Vol.88 (1), p.25-35
Hauptverfasser: de Vekki, D. A., Il’ina, M. A., Skvortsov, N. K.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Ethers
Hydrosilylation
Platinum
Radiation
Silicon
Silicon compounds
Silicon dioxide
Sulfur
Sulfur compounds
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Zusammenfassung:Hydrosilylation of allyl ethyl, allyl butyl, allyl glycidyl, allyl benzyl, and allyl phenyl ethers by 1,1,3,3-tetramethyldisiloxane in the presence of supported sulfur-containing platinum(II) complexes with the general formula [{SiO 2 }O 2S i(Me)(CH 2 ) 3 SR] 2 PtCl 2 (R = Bu, Hex, Bn; {SiO 2 } is silica surface) and side processes have been studied.
ISSN:1070-3632
1608-3350
DOI:10.1134/S107036321801005X