Bromine-rich complexes of bismuth: experimental and theoretical studies
Three novel polybromide complexes of bismuth( iii ) - (2,6-MePyH) 3 [BiBr 5 (Br 3 )] ( 1 ), (H 2 bpp){[BiBr 5 ](Br 2 )} ( 2 ) and (3-ClPyH) 2 {[BiBr 5 ](Br 2 )} ( 3 ) - were synthesized. The results of an extended screening involving a set of organic cations resulting in the formation/non-formation...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2018, Vol.47 (8), p.2683-2689 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Three novel polybromide complexes of bismuth(
iii
) - (2,6-MePyH)
3
[BiBr
5
(Br
3
)] (
1
), (H
2
bpp){[BiBr
5
](Br
2
)} (
2
) and (3-ClPyH)
2
{[BiBr
5
](Br
2
)} (
3
) - were synthesized. The results of an extended screening involving a set of organic cations resulting in the formation/non-formation of Bi(
iii
) polybromides are presented and discussed. The nature of Br Br interactions in Bi(
iii
) polybromides was investigated by theoretical methods, enabling the estimation of their energies.
Three novel polybromide complexes of bismuth(
iii
) - (2,6-MePyH)
3
[BiBr
5
(Br
3
)] (
1
), (H
2
bpp){[BiBr
5
](Br
2
)} (
2
) and (3-ClPyH)
2
{[BiBr
5
](Br
2
)} (
3
) - were synthesized. |
|---|---|
| ISSN: | 1477-9226 1477-9234 |
| DOI: | 10.1039/c7dt04779g |