Solution-processed single crystal microsheets of a novel dimeric phthalocyanine-involved triple-decker for high-performance ambipolar organic field effect transistors

Well-defined single crystal microsheets of a novel dimeric phthalocyanine involved sandwich-type triple-decker complex [Pc(SC 6 H 13 ) 8 ] 2 Eu 2 [BiPc(SC 6 H 13 ) 12 ]Eu 2 [Pc(SC 6 H 13 ) 8 ] 2 ( 1 ) are successfully prepared via a facile solution process. High-performance single crystal OFETs with a hole mobility of 18 cm 2 V −1 s −1 and an electron mobility of 0.3 cm 2 V −1 s −1 are obtained. Single-crystal microsheets of a novel dimeric phthalocyanine are successfully obtained via a facile solution process with excellent carrier mobilities of 18 cm 2 V −1 s −1 for hole and 0.3 cm 2 V −1 s −1 for electron, respectively.