A mononuclear manganese()-hydroperoxo complex: synthesis by activating dioxygen and reactivity in electrophilic and nucleophilic reactions
We report the synthesis of manganese( iii )-peroxo (Mn III (O 2 )) and manganese( iii )-hydroperoxo (Mn III (O 2 H)) complexes by activating dioxygen (O 2 ) and the amphoteric reactivity of the Mn( iii )-hydroperoxo complex in electrophilic and nucleophilic reactions. A manganese( iii )-peroxo compl...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2018, Vol.54 (1), p.129-1212 |
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| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | We report the synthesis of manganese(
iii
)-peroxo (Mn
III
(O
2
)) and manganese(
iii
)-hydroperoxo (Mn
III
(O
2
H)) complexes by activating dioxygen (O
2
) and the amphoteric reactivity of the Mn(
iii
)-hydroperoxo complex in electrophilic and nucleophilic reactions.
A manganese(
iii
)-peroxo complex was synthesized by activating dioxygen (O
2
) and the amphoteric reactivity of a manganese(
iii
)-hydroperoxo complex was demonstrated in electrophilic and nucleophilic reactions. |
|---|---|
| ISSN: | 1359-7345 1364-548X |
| DOI: | 10.1039/c7cc09492b |