Effect of Electrodeposition Potential on Surface Free Energy and Supercapacitance of MnO2 Thin Films

The effect of anodic deposition potential on the supercapacitance of manganese dioxide (MnO 2 ) and effect of surface free energy (SFE) on the supercapacitance are discussed. MnO 2 thin films have been synthesized using a potentiostatic electrodeposition method. Their structure, morphology, wettabil...

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Veröffentlicht in:Journal of electronic materials 2018-05, Vol.47 (5), p.2731-2738
Hauptverfasser: Relekar, B. P., Mahadik, S. A., Jadhav, S. T., Patil, A. S., Koli, R. R., Lohar, G. M., Fulari, V. J.
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Sprache:eng
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Zusammenfassung:The effect of anodic deposition potential on the supercapacitance of manganese dioxide (MnO 2 ) and effect of surface free energy (SFE) on the supercapacitance are discussed. MnO 2 thin films have been synthesized using a potentiostatic electrodeposition method. Their structure, morphology, wettability, electrochemical properties and supercapacitance are discussed. The observed specific capacitance ( C s ) of MnO 2 thin films is 127 F/g for the deposition potential at 1.20 V/Ag/AgCl. These films also show better stability for over 1000 cycles. The porous MnO 2 thin films lead to high SFE and a corresponding high value of specific capacitance.
ISSN:0361-5235
1543-186X
DOI:10.1007/s11664-018-6109-9