Synthesis and Characterization of Barium Amidoborane

Barium amidoborane was synthesized for the first time by the reaction of metal barium with ammonia borane. The compound was characterized by the methods of the solid-phase 11 B NMR and IR spectroscopy and elemental analysis. It was shown by simultaneous thermal analysis that hydrogen is the only vol...

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Veröffentlicht in:	Russian journal of general chemistry 2017-12, Vol.87 (12), p.2875-2877
Hauptverfasser:	Shcherbina, N. A., Kazakov, I. V., Timoshkin, A. Yu
Format:	Artikel
Sprache:	eng
Schlagworte:	Ammonia Barium Chemical synthesis Chemistry Chemistry and Materials Science Chemistry/Food Science Infrared spectroscopy Letters to the Editor NMR Nuclear magnetic resonance Thermal analysis
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Beschreibung
Zusammenfassung:	Barium amidoborane was synthesized for the first time by the reaction of metal barium with ammonia borane. The compound was characterized by the methods of the solid-phase 11 B NMR and IR spectroscopy and elemental analysis. It was shown by simultaneous thermal analysis that hydrogen is the only volatile product of barium amidoborane decomposition in the temperature range 50–240°C.
ISSN:	1070-3632 1608-3350
DOI:	10.1134/S1070363217120192