High-performance symmetrical supercapacitor based on poly(3,4)-ethylenedioxythiophene/graphene oxide/iron oxide ternary composite

Poly(3,4)-ethylenedioxythiophene/graphene oxide/iron oxide (PEDOT/GO/Fe 2 O 3 ) ternary composite was synthesized using a simple one-step electropolymerization. The electrochemical studies showed that the specific capacitance of PEDOT/GO/Fe 2 O 3 composite was three times higher (221 F g − 1 ) than...

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Veröffentlicht in:Journal of materials science. Materials in electronics 2018-04, Vol.29 (8), p.6916-6923
Hauptverfasser: Azman, Nur Hawa Nabilah, Mamat, Md Shuhazlly, Lim, Hong Ngee, Sulaiman, Yusran
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Sprache:eng
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Zusammenfassung:Poly(3,4)-ethylenedioxythiophene/graphene oxide/iron oxide (PEDOT/GO/Fe 2 O 3 ) ternary composite was synthesized using a simple one-step electropolymerization. The electrochemical studies showed that the specific capacitance of PEDOT/GO/Fe 2 O 3 composite was three times higher (221 F g − 1 ) than the binary composite of PEDOT/GO which was 73 F g − 1 at 25 mV s − 1 . The upsurge performance was believed to be contributed from anchoring particles of Fe 2 O 3 on the wrinkly PEDOT/GO that acted as a spacer in order to maximize the utilization of the electroactive materials for electrochemical reaction. Furthermore, the PEDOT/GO/Fe 2 O 3 composite was also able to attain a specific power of 8 Wh kg − 1 at a specific power of 493 W kg − 1 at 1 A g − 1 and exhibited excellent long-term stability performance even after 1000 cycles owing to the high mechanical strength provided by GO. These performances make PEDOT/GO/Fe 2 O 3 composite as a promising electrode material for supercapacitor.
ISSN:0957-4522
1573-482X
DOI:10.1007/s10854-018-8678-z