High-performance symmetrical supercapacitor based on poly(3,4)-ethylenedioxythiophene/graphene oxide/iron oxide ternary composite
Poly(3,4)-ethylenedioxythiophene/graphene oxide/iron oxide (PEDOT/GO/Fe 2 O 3 ) ternary composite was synthesized using a simple one-step electropolymerization. The electrochemical studies showed that the specific capacitance of PEDOT/GO/Fe 2 O 3 composite was three times higher (221 F g − 1 ) than...
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Veröffentlicht in: | Journal of materials science. Materials in electronics 2018-04, Vol.29 (8), p.6916-6923 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
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Zusammenfassung: | Poly(3,4)-ethylenedioxythiophene/graphene oxide/iron oxide (PEDOT/GO/Fe
2
O
3
) ternary composite was synthesized using a simple one-step electropolymerization. The electrochemical studies showed that the specific capacitance of PEDOT/GO/Fe
2
O
3
composite was three times higher (221 F g
− 1
) than the binary composite of PEDOT/GO which was 73 F g
− 1
at 25 mV s
− 1
. The upsurge performance was believed to be contributed from anchoring particles of Fe
2
O
3
on the wrinkly PEDOT/GO that acted as a spacer in order to maximize the utilization of the electroactive materials for electrochemical reaction. Furthermore, the PEDOT/GO/Fe
2
O
3
composite was also able to attain a specific power of 8 Wh kg
− 1
at a specific power of 493 W kg
− 1
at 1 A g
− 1
and exhibited excellent long-term stability performance even after 1000 cycles owing to the high mechanical strength provided by GO. These performances make PEDOT/GO/Fe
2
O
3
composite as a promising electrode material for supercapacitor. |
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ISSN: | 0957-4522 1573-482X |
DOI: | 10.1007/s10854-018-8678-z |