Shortcut method for kinetically controlled reactive distillation systems

A geometric‐based shortcut method for reactive distillation is addressed. The rectification body method for nonreactive distillation, the concept of critical Damköhler numbers, and the geometric design method for reactive distillation are combined with a new eigenvector analysis of pinch points. Thi...

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Veröffentlicht in:AIChE journal 2003-06, Vol.49 (6), p.1471-1487
Hauptverfasser: Lee, J. W., Brüggemann, S., Marquardt, W.
Format: Artikel
Sprache:eng
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Zusammenfassung:A geometric‐based shortcut method for reactive distillation is addressed. The rectification body method for nonreactive distillation, the concept of critical Damköhler numbers, and the geometric design method for reactive distillation are combined with a new eigenvector analysis of pinch points. This shortcut method provides a minimum or reasonable Damköhler number for a given heat duty, as well as the design implication of how to effectively distribute reaction zones inside a column. This method can be used for a fast screening of process design alternatives and for an initialization of rigorous optimization.
ISSN:0001-1541
1547-5905
DOI:10.1002/aic.690490611