Carbon and few-layer MoS2 nanosheets co-modified TiO2 nanosheets with enhanced electrochemical properties for lithium storage

Carbon and few-layer MoS2 nanosheets co- modified TiO2 nanocomposites (defined as MoS2-C@TiO2) were prepared through a facile one-step pyrolysis reaction technique. In this unique nanostructure, the TiO2 nanosh- eets with stable structure serve as the backbones, and carbon coating and few-layer MoS2...

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Veröffentlicht in:Rare metals 2018-02, Vol.37 (2), p.107-117
Hauptverfasser: Lu, Hui-Hui, Shi, Chun-Sheng, Zhao, Nai-Qin, Liu, En-Zuo, He, Chun-Nian, He, Fang
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Sprache:eng
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Zusammenfassung:Carbon and few-layer MoS2 nanosheets co- modified TiO2 nanocomposites (defined as MoS2-C@TiO2) were prepared through a facile one-step pyrolysis reaction technique. In this unique nanostructure, the TiO2 nanosh- eets with stable structure serve as the backbones, and carbon coating and few-layer MoS2 tightly adhere onto the surface of the TiO2. It needs to be pointed out that the carbon coating improves the overall electronic conductivity and the few-layer MoS2 facilitates the diffusion of lithium ions and offers more active sites for lithium-ion storage. As a result, when evaluated as lithium-ion battery anodes, the MoS2-C@TiO2 nanocomposites exhibit markedly enhanced lithium storage capability compared with pure TiO2. A high specific capacity of 180 mA.h.g-1 has been achieved during the preliminary cycles, and the specific capacity can maintain 160 mA.h.g-1 at a high current density of 1C (1C=167 mA.g-1) even after 300 discharge/ charge cycles, indicating the great potential of the MoS2- C@TiO2 on energy storage.
ISSN:1001-0521
1867-7185
DOI:10.1007/s12598-017-0983-9