Frontispiece: Extending Long‐lived Charge Separation Between Donor and Acceptor Blocks in Novel Copolymer Architectures Featuring a Sensitizer Core
Electron donor and acceptor polymer chains were connected via a Ru(II) dye to form a linear photoredox‐active architecture predestined for efficient light‐induced charge separation. The modular assembling strategy benefits from the separately prepared units and highly efficient coupling reactions. U...
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| Veröffentlicht in: | Chemistry : a European journal 2017-11, Vol.23 (65), p.n/a |
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| container_issue | 65 |
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| container_title | Chemistry : a European journal |
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| creator | Schroot, Robert Schlotthauer, Tina Dietzek, Benjamin Jäger, Michael Schubert, Ulrich S |
| description | Electron donor and acceptor polymer chains were connected via a Ru(II) dye to form a linear photoredox‐active architecture predestined for efficient light‐induced charge separation. The modular assembling strategy benefits from the separately prepared units and highly efficient coupling reactions. Upon excitation of the dye a long‐lived charge separation in the μs time scale is observed with significantly reduced recombination in comparison to low‐molecular model systems or non‐conjugated congeners. For more information see the Full Paper by M. Jäger, U. S. Schubert et al. on page 16484 ff. |
| doi_str_mv | 10.1002/chem.201786564 |
| format | Article |
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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Chemical reactions Chemistry complex chemistry Congeners Coupling (molecular) donor–acceptor systems Dyes electron transfer Light effects Recombination ruthenium Separation time-resolved spectroscopy |
| title | Frontispiece: Extending Long‐lived Charge Separation Between Donor and Acceptor Blocks in Novel Copolymer Architectures Featuring a Sensitizer Core |
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