Frontispiece: Extending Long‐lived Charge Separation Between Donor and Acceptor Blocks in Novel Copolymer Architectures Featuring a Sensitizer Core

Electron donor and acceptor polymer chains were connected via a Ru(II) dye to form a linear photoredox‐active architecture predestined for efficient light‐induced charge separation. The modular assembling strategy benefits from the separately prepared units and highly efficient coupling reactions. U...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemistry : a European journal 2017-11, Vol.23 (65), p.n/a
Hauptverfasser: Schroot, Robert, Schlotthauer, Tina, Dietzek, Benjamin, Jäger, Michael, Schubert, Ulrich S
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Electron donor and acceptor polymer chains were connected via a Ru(II) dye to form a linear photoredox‐active architecture predestined for efficient light‐induced charge separation. The modular assembling strategy benefits from the separately prepared units and highly efficient coupling reactions. Upon excitation of the dye a long‐lived charge separation in the μs time scale is observed with significantly reduced recombination in comparison to low‐molecular model systems or non‐conjugated congeners. For more information see the Full Paper by M. Jäger, U. S. Schubert et al. on page 16484 ff.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201786564