Suppression of impurity phases and the study of magnetic and magnetocaloric properties of Ho2Co2Al intermetallic compound

•Suppression of impurity phases in Ho2Co2Al intermetallic is achieved.•The magnetic and magnetocaloric properties of the Ho2Co2Al have been studied.•Large magnetic entropy change and good refrigerant capacity were obtained. The R2Co2Al compounds (R=Tb, Dy, Ho, Er, Tm) are known to contain RCoAl-type impurity. In order to suppress the impurity phase in Ho2Co2Al intermetallic compound, nonstoichiometric samples with excess rare-earth Ho were prepared and annealed. Structural analysis indicates that annealed nonstoichiometric Ho42Co40Al20 sample, with 2at% excess Ho, comprises the Ho2Co2Al phase and minor traces of Ho2O3 oxide. Magnetic and magnetocaloric properties of the sample have been studied in detail. The alloy undergoes three phase transitions at 9K, 21K and 30K. The multiple transitions and broadening effect of second-order phase transitions (SOT) on peak magnetic entropy change (−ΔSM), result in good refrigerant capacities (RCareas) of 136.9 and 437J/kg under field changes (ΔH) of 2 and 5T, respectively. These values of RCarea and their corresponding large −ΔSM peak magnitudes of 9.1 and 18.4J/kgK under ΔH=2 and 5T, respectively, make Ho2Co2Al a promising and competitively good candidate magnetic refrigerant for low temperature cooling applications such as liquefaction of hydrogen gas.