New Platinum Alloy Catalysts for Oxygen Electroreduction Based on Alkaline Earth Metals

The energy efficiency of polymer electrolyte membrane fuel cells is mainly limited by overpotentials related to the oxygen reduction reaction (ORR). In this paper, we present new platinum alloys which are active for the ORR and based on alloying Pt with very abundant elements, such as Ca. Theoretical calculations suggested that Pt 5 Ca and Pt 5 Sr should be active for the ORR. Electrochemical measurements show that the activity of sputter-cleaned polycrystalline Pt 5 Ca and Pt 5 Sr electrodes is enhanced by a factor of 5–7 relative to polycrystalline Pt. Accelerated stability testing shows that after 10,000 electrochemical cycles, the alloys still retain over half their activity. The stability is thus not quite on par with the similar Pt-lanthanide alloys, possibly due to the somewhat lower heat of formation. Graphical Abstract Left: The structure of Pt 5 Ca with a compressed Pt overlayer. The compression increases activity for the Oxygen Reduction Reaction (ORR). Right: The measured ORR activity of the best Platinum alloys.