Influence of 45S5 Bioglass addition on microstructure and properties of ultrafine grained (Mg-4Y-5.5Dy-0.5Zr) alloy

[Display omitted] •Ultrafine grained composites were formed by consolidating mechanically alloyed powders.•Mechanical properties were sensitive to the content of 45S5 Bioglass in Mg-4Y-5.5Dy-0.5Zr alloy.•Fluoride treated composites displayed superior corrosion resistance in Ringer solution.•Composit...

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Veröffentlicht in:Materials science & engineering. B, Solid-state materials for advanced technology Solid-state materials for advanced technology, 2017-05, Vol.219, p.28-36
Hauptverfasser: Kowalski, K., Jurczyk, M.U., Wirstlein, P.K., Jakubowicz, J., Jurczyk, M.
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container_title Materials science & engineering. B, Solid-state materials for advanced technology
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creator Kowalski, K.
Jurczyk, M.U.
Wirstlein, P.K.
Jakubowicz, J.
Jurczyk, M.
description [Display omitted] •Ultrafine grained composites were formed by consolidating mechanically alloyed powders.•Mechanical properties were sensitive to the content of 45S5 Bioglass in Mg-4Y-5.5Dy-0.5Zr alloy.•Fluoride treated composites displayed superior corrosion resistance in Ringer solution.•Composites modified with MgF2 have a higher degree of biocompatibility in comparison with the unmodified reference material. Bulk samples of an ultrafine grained (Mg-4Y-5.5Dy-0.5Zr)-x wt% 45S5 Bioglass (x=0, 5) and (Mg-4Y-5.5Dy-0.5Zr)-5 wt% 45S5 Bioglass-1 wt% Ag composites have been synthesized by consolidating mechanically alloyed powders. The influence of the chemical composition on the microstructure, mechanical properties and corrosion behavior of bulk composites were studied. The sintering of (Mg-4Y-5.5Dy-0.5Zr)-5 wt% 45S5 Bioglass powders led to the formation of a bulk composite with grain size of approx. 95nm. The corrosion behavior of Mg-based composites before and after hydrofluoric acid treatment was also investigated. The ultrafine grained (Mg-4Y-5.5Dy-0.5Zr)-5 wt% 45S5 Bioglass composite was more corrosion resistant than the bulk Mg-4Y-5.5Dy-0.5Zr alloy after HF treatment. The in vitro biocompatibility of synthesized composites was evaluated and compared with microcrystalline magnesium. Magnesium, (Mg-4Y-5.5Dy-0.5Zr)-5 wt% 45S5 Bioglass and (Mg-4Y-5.5Dy-0.5Zr)-5 wt% 45S5 Bioglass-1 wt% Ag composites modified with MgF2 have a higher degree of biocompatibility in comparison with the unmodified reference material.
doi_str_mv 10.1016/j.mseb.2017.02.010
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Bulk samples of an ultrafine grained (Mg-4Y-5.5Dy-0.5Zr)-x wt% 45S5 Bioglass (x=0, 5) and (Mg-4Y-5.5Dy-0.5Zr)-5 wt% 45S5 Bioglass-1 wt% Ag composites have been synthesized by consolidating mechanically alloyed powders. The influence of the chemical composition on the microstructure, mechanical properties and corrosion behavior of bulk composites were studied. The sintering of (Mg-4Y-5.5Dy-0.5Zr)-5 wt% 45S5 Bioglass powders led to the formation of a bulk composite with grain size of approx. 95nm. The corrosion behavior of Mg-based composites before and after hydrofluoric acid treatment was also investigated. The ultrafine grained (Mg-4Y-5.5Dy-0.5Zr)-5 wt% 45S5 Bioglass composite was more corrosion resistant than the bulk Mg-4Y-5.5Dy-0.5Zr alloy after HF treatment. The in vitro biocompatibility of synthesized composites was evaluated and compared with microcrystalline magnesium. Magnesium, (Mg-4Y-5.5Dy-0.5Zr)-5 wt% 45S5 Bioglass and (Mg-4Y-5.5Dy-0.5Zr)-5 wt% 45S5 Bioglass-1 wt% Ag composites modified with MgF2 have a higher degree of biocompatibility in comparison with the unmodified reference material.</description><identifier>ISSN: 0921-5107</identifier><identifier>EISSN: 1873-4944</identifier><identifier>DOI: 10.1016/j.mseb.2017.02.010</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>45S5 Bioglass ; Alloy powders ; Alloys ; Biocompatibility ; Bioglass ; Chemical synthesis ; Consolidation ; Corrosion resistant alloys ; Grain size ; Hafnium base alloys ; Hydrofluoric acid ; Magnesium ; Magnesium base alloys ; Mechanical alloying ; Mechanical properties ; Microstructure ; Sintering ; Sintering (powder metallurgy) ; Ultrafine grain</subject><ispartof>Materials science &amp; engineering. 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B, Solid-state materials for advanced technology</title><description>[Display omitted] •Ultrafine grained composites were formed by consolidating mechanically alloyed powders.•Mechanical properties were sensitive to the content of 45S5 Bioglass in Mg-4Y-5.5Dy-0.5Zr alloy.•Fluoride treated composites displayed superior corrosion resistance in Ringer solution.•Composites modified with MgF2 have a higher degree of biocompatibility in comparison with the unmodified reference material. Bulk samples of an ultrafine grained (Mg-4Y-5.5Dy-0.5Zr)-x wt% 45S5 Bioglass (x=0, 5) and (Mg-4Y-5.5Dy-0.5Zr)-5 wt% 45S5 Bioglass-1 wt% Ag composites have been synthesized by consolidating mechanically alloyed powders. The influence of the chemical composition on the microstructure, mechanical properties and corrosion behavior of bulk composites were studied. The sintering of (Mg-4Y-5.5Dy-0.5Zr)-5 wt% 45S5 Bioglass powders led to the formation of a bulk composite with grain size of approx. 95nm. The corrosion behavior of Mg-based composites before and after hydrofluoric acid treatment was also investigated. The ultrafine grained (Mg-4Y-5.5Dy-0.5Zr)-5 wt% 45S5 Bioglass composite was more corrosion resistant than the bulk Mg-4Y-5.5Dy-0.5Zr alloy after HF treatment. The in vitro biocompatibility of synthesized composites was evaluated and compared with microcrystalline magnesium. Magnesium, (Mg-4Y-5.5Dy-0.5Zr)-5 wt% 45S5 Bioglass and (Mg-4Y-5.5Dy-0.5Zr)-5 wt% 45S5 Bioglass-1 wt% Ag composites modified with MgF2 have a higher degree of biocompatibility in comparison with the unmodified reference material.</description><subject>45S5 Bioglass</subject><subject>Alloy powders</subject><subject>Alloys</subject><subject>Biocompatibility</subject><subject>Bioglass</subject><subject>Chemical synthesis</subject><subject>Consolidation</subject><subject>Corrosion resistant alloys</subject><subject>Grain size</subject><subject>Hafnium base alloys</subject><subject>Hydrofluoric acid</subject><subject>Magnesium</subject><subject>Magnesium base alloys</subject><subject>Mechanical alloying</subject><subject>Mechanical properties</subject><subject>Microstructure</subject><subject>Sintering</subject><subject>Sintering (powder metallurgy)</subject><subject>Ultrafine grain</subject><issn>0921-5107</issn><issn>1873-4944</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp9kEtLxDAUhYMoOI7-AVcBN7povXk1LbjxrTDiQl3oJqRJOmTotGPSCvPvTRnXwoWzOefecz-ETgnkBEhxucrX0dU5BSJzoDkQ2EMzUkqW8YrzfTSDipJMEJCH6CjGFQAQSukMxeeuaUfXGYf7BnPxJvCN75etjhFra_3g-w6nWXsT-jiE0QxjcFh3Fm9Cv3Fh8C5O0bEdgm585_Ay6CQWn78sM_6ZiVzcbTPIxVe4wLpt--0xOmh0G93Jn87Rx8P9--1Ttnh9fL69XmSG0XLIKieBsELwMg0xTBagbe04E4WsSW0tNIWhtdGkMazggolKgiglrxkYais2R2e7vanp9-jioFb9GLp0UpGKU8krycrkojvX9GAMrlGb4Nc6bBUBNcFVKzXBVRNcBVQluCl0tQu51P_Hu6Ci8RNF64Mzg7K9_y_-CyCFgLc</recordid><startdate>201705</startdate><enddate>201705</enddate><creator>Kowalski, K.</creator><creator>Jurczyk, M.U.</creator><creator>Wirstlein, P.K.</creator><creator>Jakubowicz, J.</creator><creator>Jurczyk, M.</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>201705</creationdate><title>Influence of 45S5 Bioglass addition on microstructure and properties of ultrafine grained (Mg-4Y-5.5Dy-0.5Zr) alloy</title><author>Kowalski, K. ; Jurczyk, M.U. ; Wirstlein, P.K. ; Jakubowicz, J. ; Jurczyk, M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c328t-9e701365485481c3760adbe43567b1bdd0f6c2bca1fc3645359705874b30c2d93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>45S5 Bioglass</topic><topic>Alloy powders</topic><topic>Alloys</topic><topic>Biocompatibility</topic><topic>Bioglass</topic><topic>Chemical synthesis</topic><topic>Consolidation</topic><topic>Corrosion resistant alloys</topic><topic>Grain size</topic><topic>Hafnium base alloys</topic><topic>Hydrofluoric acid</topic><topic>Magnesium</topic><topic>Magnesium base alloys</topic><topic>Mechanical alloying</topic><topic>Mechanical properties</topic><topic>Microstructure</topic><topic>Sintering</topic><topic>Sintering (powder metallurgy)</topic><topic>Ultrafine grain</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kowalski, K.</creatorcontrib><creatorcontrib>Jurczyk, M.U.</creatorcontrib><creatorcontrib>Wirstlein, P.K.</creatorcontrib><creatorcontrib>Jakubowicz, J.</creatorcontrib><creatorcontrib>Jurczyk, M.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Materials science &amp; engineering. B, Solid-state materials for advanced technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kowalski, K.</au><au>Jurczyk, M.U.</au><au>Wirstlein, P.K.</au><au>Jakubowicz, J.</au><au>Jurczyk, M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Influence of 45S5 Bioglass addition on microstructure and properties of ultrafine grained (Mg-4Y-5.5Dy-0.5Zr) alloy</atitle><jtitle>Materials science &amp; engineering. B, Solid-state materials for advanced technology</jtitle><date>2017-05</date><risdate>2017</risdate><volume>219</volume><spage>28</spage><epage>36</epage><pages>28-36</pages><issn>0921-5107</issn><eissn>1873-4944</eissn><abstract>[Display omitted] •Ultrafine grained composites were formed by consolidating mechanically alloyed powders.•Mechanical properties were sensitive to the content of 45S5 Bioglass in Mg-4Y-5.5Dy-0.5Zr alloy.•Fluoride treated composites displayed superior corrosion resistance in Ringer solution.•Composites modified with MgF2 have a higher degree of biocompatibility in comparison with the unmodified reference material. Bulk samples of an ultrafine grained (Mg-4Y-5.5Dy-0.5Zr)-x wt% 45S5 Bioglass (x=0, 5) and (Mg-4Y-5.5Dy-0.5Zr)-5 wt% 45S5 Bioglass-1 wt% Ag composites have been synthesized by consolidating mechanically alloyed powders. The influence of the chemical composition on the microstructure, mechanical properties and corrosion behavior of bulk composites were studied. The sintering of (Mg-4Y-5.5Dy-0.5Zr)-5 wt% 45S5 Bioglass powders led to the formation of a bulk composite with grain size of approx. 95nm. The corrosion behavior of Mg-based composites before and after hydrofluoric acid treatment was also investigated. The ultrafine grained (Mg-4Y-5.5Dy-0.5Zr)-5 wt% 45S5 Bioglass composite was more corrosion resistant than the bulk Mg-4Y-5.5Dy-0.5Zr alloy after HF treatment. The in vitro biocompatibility of synthesized composites was evaluated and compared with microcrystalline magnesium. Magnesium, (Mg-4Y-5.5Dy-0.5Zr)-5 wt% 45S5 Bioglass and (Mg-4Y-5.5Dy-0.5Zr)-5 wt% 45S5 Bioglass-1 wt% Ag composites modified with MgF2 have a higher degree of biocompatibility in comparison with the unmodified reference material.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.mseb.2017.02.010</doi><tpages>9</tpages></addata></record>
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1873-4944
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subjects 45S5 Bioglass
Alloy powders
Alloys
Biocompatibility
Bioglass
Chemical synthesis
Consolidation
Corrosion resistant alloys
Grain size
Hafnium base alloys
Hydrofluoric acid
Magnesium
Magnesium base alloys
Mechanical alloying
Mechanical properties
Microstructure
Sintering
Sintering (powder metallurgy)
Ultrafine grain
title Influence of 45S5 Bioglass addition on microstructure and properties of ultrafine grained (Mg-4Y-5.5Dy-0.5Zr) alloy
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