Frontispiece: A Consecutive C−H Functionalization Triggered by Oxidation of Active sp3 C−H Bonds: Construction of 3,4‐Dihydroquinoline‐3‐one Derivatives
Construction of 3,4‐dihydroquinoline‐3‐ones is achieved by radical cation‐initiated aerobic oxidation. In this transformation, the active sp3 C−H bonds of glycines act as the “Achilles′ heel”, triggering the consecutive oxidation of the inert C−H bonds. Furthermore, one heterocylic ring with a quate...
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Veröffentlicht in: | Chemistry : a European journal 2017-09, Vol.23 (53), p.n/a |
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Hauptverfasser: | , , , , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Construction of 3,4‐dihydroquinoline‐3‐ones is achieved by radical cation‐initiated aerobic oxidation. In this transformation, the active sp3 C−H bonds of glycines act as the “Achilles′ heel”, triggering the consecutive oxidation of the inert C−H bonds. Furthermore, one heterocylic ring with a quaternary carbon center is also constructed. More information can be found in the Communication by X. Jia et al. on page 12980 ff. |
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ISSN: | 0947-6539 1521-3765 |
DOI: | 10.1002/chem.201785363 |