Frontispiece: A Consecutive C−H Functionalization Triggered by Oxidation of Active sp3 C−H Bonds: Construction of 3,4‐Dihydroquinoline‐3‐one Derivatives

Construction of 3,4‐dihydroquinoline‐3‐ones is achieved by radical cation‐initiated aerobic oxidation. In this transformation, the active sp3 C−H bonds of glycines act as the “Achilles′ heel”, triggering the consecutive oxidation of the inert C−H bonds. Furthermore, one heterocylic ring with a quate...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemistry : a European journal 2017-09, Vol.23 (53), p.n/a
Hauptverfasser: Jia, Xiaodong, Hou, Wentao, Shao, Yu, Yuan, Yu, Chen, Qian, Li, Pengfei, Liu, Xiaofei, Ji, Honghe
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Construction of 3,4‐dihydroquinoline‐3‐ones is achieved by radical cation‐initiated aerobic oxidation. In this transformation, the active sp3 C−H bonds of glycines act as the “Achilles′ heel”, triggering the consecutive oxidation of the inert C−H bonds. Furthermore, one heterocylic ring with a quaternary carbon center is also constructed. More information can be found in the Communication by X. Jia et al. on page 12980 ff.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201785363